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激光热致相变核-壳微胶囊的合成与性能 被引量:1

Synthesis and property of core-shell microsphere with phase-transfering by infrared laser
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摘要 以甲基丙烯酸甲酯作为主要的核单体,甲基丙烯酸缩水甘油酯作为壳单体,叔胺盐作为壳的改性剂,合成了平均粒径为55nm具有激光热致相变性能的核壳微胶囊。用红外光谱对其结构进行了表征;用透射电镜观察了微胶囊形貌;用示差量热分析法、热重分析法测定了热性能、接触角仪测定了相变前后的亲水性,探讨了对相变效果的影响因素。核聚合物的玻璃化转变温度为56.2℃,壳聚合物的玻璃化转变温度为85.3℃;该微胶囊感激光后发生相变,接触角由初始的20°变为93°。 A novel microsphere of an average diameter 55 nm was synthesized. The shell of the microsphere converted from hydrophilicity into hydrophobic nature by infrared laser. The core was synthesized mainly with methyl methylacrylate (MMA). The shell was synthesized with glycidyl methylacrylate (GMA) before it was modified by quarternary ammonium salt. The configuration of the micro-sphere was characterized by infrared spectrum (IR) and transparent electronic microscope (TEM) ; and its calorific property was characterized by differential scanning calorimeter (DSC) and thermogravimetric analysis (TG). The hydrophilic ability of the microsphere was tested by contact angle of water. The effects on the phase transformation were discussed. As a result, the glass transferring temperature (Tg) of the core is 56.2℃ and the Tg of the shell is 85.3℃ . The value of the contact angle of water on the coating of core-shell microsphere was 20° and became 93° after radiation from infrared laser.
出处 《北京化工大学学报(自然科学版)》 CAS CSCD 北大核心 2005年第3期33-37,共5页 Journal of Beijing University of Chemical Technology(Natural Science Edition)
基金 北京市教委"科技发展计划"项目(00kj129)
关键词 核-壳乳液聚合 叔胺盐改性 830nm激光 相变 core-shell latex polymerization modifying by quarternary ammonium salt 830 nm laser phase transformation
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  • 1曹同玉 刘庆普 胡金生.聚合物乳液合成原理性能及应用[M].北京:化学工业出版社,2002.304-310,474-477.
  • 2陈寿安 李松泰.无乳化剂乳化聚合技术回顾[J].Colloid Interface Soc,1995,8(2):67-67.
  • 3Christopher J Ferguson, Geogory T Russell, Robert G Gilbert. Synthesis of laties with hydrophobic cores and poly(vinyl acetate) shells[J ]. Polymer, 2003, 44 : 2607 -2619.
  • 4赵科,孙培勤,刘大壮.VAc/BA核壳乳液聚合乳胶粒形态演化[J].高分子学报,2002,12(2):257-260. 被引量:9
  • 5Min T I, Klein A, EI-Aasser M S, et al. New aspects of core-shell emulsion polymerization polybutlacrylate and styrene pair system[J]. Org Coat Appl Polym Sci Proc,1981,46:134 - 321.
  • 6大森英三.功能性丙烯酸树脂[M].北京:化学工业出版社,1993..

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