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丙酮气相一步法合成甲基异丁基酮催化剂 被引量:2

Catalysts for Synthesis of Methyl Isobutyl Ketone from Acetone with One Step Reaction
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摘要 用浸渍法制备了丙酮一步法合成甲基异丁基酮催化剂,用X射线衍射分析了催化剂的结构,讨论了不同质量含量的Cu、MgO对于丙酮转化为甲基异丁基酮的影响,结果发现当Cu含量为4%(质量分数),MgO含量为20%(质量分数)时,丙酮的转化率最高,为73.96%,并对反应机理进行了初步探讨。 Catalysts for synthesis of methyl isobutyl ketone [MIBK] from acetone with one step reaction were prepared by impregnated method. The structure of material was analysed through X-ray diffraction and the effects of different content of Cu and MgO on acetones converted to MIBK were studied . The results showed the highest conversion of acetone was 73.96 % when the content of Cu was 4 % and that of MgO, 20 %. At last the reaction principle was preliminarily discussed.
出处 《化学工业与工程》 CAS 2005年第5期358-361,共4页 Chemical Industry and Engineering
关键词 丙酮 甲基异丁基酮 一步法 浸渍法 acetone methyl isobutyl ketone one step reaction impregnated method
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  • 1张明珠,刘月霞,单学蕾,关乃佳,陶克毅.稀土改性Ni/γ-Al_2O_3催化剂合成甲基异丁基酮的研究[J].化学工业与工程,1996,13(3):38-43. 被引量:10
  • 2何荟娟.甲基异丁基酮[J].精细石油化工,1992,9(3):63-66. 被引量:9
  • 3阎淑萍,张士莹,任少锋,刘丰臻,刘红兵.甲基异丁基酮的生产方法及其应用[J].河北化工,1998(2):37-40. 被引量:6
  • 4关乃佳,单学蕾,赵东,林福胜.Ni、Pd/Al_2O_3对丙酮加氢一步合成甲基异丁基酮性能比较[J].高等学校化学学报,1997,18(11):1862-1865. 被引量:10
  • 5MELO L, GIANNETTO G, ALYAREZ F, et al. Synthesis of methyl isobutyl ketone using Pt-H [ Al ] ZSM5 bifunctional catalysts[J]. Catal Lett, 1998,51:207 - 212.
  • 6MELO L, LLANOS A, MEDIAVILLA M, et al. Acetone transformation over Pt-H[Al]ZSM5 catalysts[J] .J Mol Catal A,2002,177:281 - 287.
  • 7SZE MING YANG, YIH MIN WU. One step synthesis of methyl isobutyl ketone over palladium supported on AlPO4-11 and SAPO- 11 [ J ] . Applied Catalysis A Genera, 2000,192(2) :11 - 220.
  • 8OLSON K D, LANE C,VA W. Process for the Condensation of Ketones[ P] . US:4 704 478,1987-11-03.
  • 9NIGAMANANDA DAS, DIDIER TICHIT, ROBERT DURAND, et al. Influence of the metal funt'tion in the "onepot" synthesis of 4-methyl-2-pentanone (methyl isobutyl ketone)from acetone over palladium supported on Mg(Al)O mixeds catalysts [ J ]. Catal Lett, 2001,71 ( 3-4 ) : 181 - 185.
  • 10GANDIA L M, MONTES M. Highly selection one-step formation of methyl isobutyl ketone from acetone with a magnesium supported nickel catalyst [ J ]. Appl Catal A,1993,101 : 1 - 6.

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