摘要
本文合成了3种轴向配位的萘酞菁硅配合物(NcSiR2,R=Cl、OH、OCH3),研究了3种萘酞菁配合物激发态性质,研究结果表明,随着轴向取代基推电子能力的逐渐增强,激发单线态寿命和激发三线态寿命逐渐缩短,产生单线态氧的能力逐渐下降。
Three kinds of axially substituted silicon naphthalocyanine compounds （NcSiR2, R=Cl, OH, OCH3） have been synthesized. Excitation properties of the compounds have been investigated. The results indicate that the life for excitation singlet and triplet states, and generation of singlet-state oxygen are reduced with increase of push electronic properties of axially substituted groups.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2005年第10期1450-1454,共5页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金(No.20141001)
黑龙江省自然科学基金(No.B01-07)资助项目
关键词
硅荼酞菁配合物
激发单线态和三线态寿命
单线念氧
silicon naphthalocyanine
life of excitation single-state and tri-state
single-state oxygen
