摘要
A novel complex of a new 1,4-dicyclohexyl cucurbituril(DCYQ6) with sodium(I) ion was synthesized, and the crystal structure was determined by X-ray diffraction technique. In this self-assembled entity both the cavity interaction of DCYQ6 included a nitrate anion and the portal interaction of the dipole carbonyls of DCYQ6 with sodium cations lead to form self assembled molecular capsules. The crystal structure of the entity shows a packing of the self assembled molecular capsules connected by hydrogen bonds of water molecules. CCDC: 271400.
A novel complex of a new 1,4-dicyclohexyl cucurbituril（DCYQ[6]） with sodium（Ⅰ） ion was synthesized, and the crystal structure was determined by X-ray diffraction technique. In this self-assembled entity both the cavity interaction of DCYQ[6] included a nitrate anion and the portal interaction of the dipole carbonyls of DCYQ [6] with sodium cations lead to form self assembled molecular capsules. The crystal structure of the entity shows a packing of the self assembled molecular capsules connected by hydrogen bonds of water molecules. CCDC： 271400.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2005年第10期1583-1588,共6页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20362003)
科技部国际科技合作重点项目计划(No.2003DF000030)
贵州省省长资金项目
贵州省国际科技合作重点项目计划(No.2005400101)
