摘要
The convalently linked porphyrin-fullerene ligand was synthesized by 1,3 dipolar cycloaddition reaction. The ligand and complexes were characterized by means of FT-IR, Uv-Vis, 1HNMR, ESI-MS and elemental analysis. The photoelectricity transform performance of the compounds was studied.The result indicated that the photovoltaic effect of （n+n） heterojunction electrode formed by MP-C60/GaAs was super, especially in the I2/I3- and O2/H2O redox couples, and photovoltaic potential was preferable.The photovoltaic performance of a MP-C60/GaAs electrode at 1-2 μm thinck MP-C60 film of appeared peak value.
The convalently linked porphyrin-fullerene ligand was synthesized by 1,3 dipolar cycloaddition reaction. The ligand and complexes were characterized by means of FT-IR, Uv-Vis, 1HNMR, ESI-MS and elemental analysis. The photoelectricity transform performance of the compounds was studied. The result indicated that the photovohaic effect of （n ＋ n） heterojunction electrode formed by MP-C60/GaAs was super, especially in the I2/I3 - and O2/H2O redox couples, and photovohaic potential was preferable. The photovohaic performance of a MP-C60/ GaAs electrode at 1 -2 μm thinck MP-C60 film of appeared peak value.
基金
ProjectsupportedbytheNatureScienceFoundationofFujianprovince(E0410001)andSelf-selectProgramofXiamenUniversity(0040-Y07008).
关键词
卟啉
富勒烯
光电性能
Porphyrin, Fullerene, Photovohaic effect
