期刊文献+

Ziegler-Natta/非茂双金属催化剂制备宽相对分子质量分布聚乙烯 被引量:4

Ziegler-Natta/Non-Metallocene Bimetallic Catalyst for Preparation of Broad Relative Molecular Mass Distribution Polyethylene
下载PDF
导出
摘要 以S iO2为载体,将Z ieg ler-Natta(Z-N)催化剂和非茂催化剂的活性组分负载在同一载体上,制得S iO2负载型Z-N/非茂双金属催化剂;研究了双金属催化剂催化乙烯聚合的动力学规律,考察Zr的负载量、n(T i)∶n(Zr)对双金属催化剂催化活性和聚乙烯产物的影响。实验结果表明,双金属催化体系中同时存在两类性质不同的活性中心,两类活性中心之间存在着协同效应;控制Zr的负载量和n(T i)∶n(Zr),可在保持较高催化活性的同时,得到宽相对分子质量分布和高熔流比的聚乙烯;采用Zr的质量分数为2.08%、n(T i)∶n(Zr)=4.45的双金属催化剂,在氢分压为0.2M Pa、总压为0.8M Pa、聚合温度为70℃、n(A l)∶n(T i+Zr)=200的条件下催化乙烯聚合时,其催化活性(每摩尔T i和Zr每小时产生的聚乙烯的质量)为4.30×105g/(m ol.h),聚乙烯的相对分子质量分布可达17.22,熔流比可达89.93。 The bimetallic catalyst was prepared by supporting Ziegler -Natta and non -metallocene active components on SiO2 carder with a special method. Ethylene polymerization kinetics on bimetallic catalyst was studied, which indicated that two different kinds of active sites existed on the catalyst. The two kinds of sites had a cooperative effect in ethylene polymerization. By controlling Zr content and n (Ti) : n (Zr)of catalyst, relative molecular mass distribution of polyethylene could be effectively broadened and bimetallic catalyst had high catalytic activity. Under following polymerization conditions:70 ℃, hydrogen pressure 0.2 MPa, total pressure 0.8 MPa,mass fraction of Zr in bimetallic catalyst 2. 08% and n (Ti) : n (Zr) = 4. 45, catalyst activity (polyethylene mass produced per mole Ti and Zr per hour)was 4.30 × 10^5 g/( mol · h)and polyethylene with relative molecular mass distribution 17.22 and melting flow ratio 89.93 could be obtained.
出处 《石油化工》 EI CAS CSCD 北大核心 2005年第11期1050-1054,共5页 Petrochemical Technology
关键词 负载 Ziegler—Natta 非茂 双金属催化剂 聚乙烯 相对分子质量分布 催化 support Ziegler - Natta non - metallocene bimetallic catalyst polyethylene relative molecular mass distribution catalysis
  • 相关文献

参考文献8

二级参考文献8

共引文献23

同被引文献90

引证文献4

二级引证文献11

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部