摘要
萘和正丁醇存在下β－环糊精诱导１－溴萘室温磷光的研究杜新贞，张勇，黄贤智，李耀群，江云宝，陈国珍（厦门大学化学系、环境科学研究中心，厦门，３６１００５）关键词１－溴萘，β－环糊精，萘，室温磷光室温下β－环糊精（β－ＣＤ）诱导的发光现象由于其不同于胶束...
Intense room temperature phosphorescence(RTP)from host-guest inclusion complex of β-cyclodextrin(β-CD)with 1-bromonaphthalene(1-BrN),stabilized by naphthalene (N)and 1-butanol(B), has been investigated, It has been confirmed that N and B are incorporated into the nonpolar cavity of β-CD as the second guest and the third one. The extra space inside the cavity is further filled by N and B, and β-CD more effectively shields 1-BrN from quenchers in aqueous solution.B completely hinders the formation of N excimer.The greater rigidity of the complex was achieved. Consequently, much more intense fluorescence of RTP appears in comparison with the ternary β-CD:1-BrN:B or β-CD:1-BrN:N complex.The limit of detection is 7. 38×10￣(-8)mol/L for 1-BrN and 1.36×10￣(-6) mol/L for N.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1996年第3期381-382,共2页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
溴萘
环糊精
萘
室温磷光
丁醇
Bromonaphthalene,β-Cyclodextrin, Naphthalene, Room temperature phosphorescence
