摘要
以NaBH4为还原剂,研究了金属离子对苯甲酰丙酮选择性还原的影响。结果发现,添加Cd2+主要得到3-羰基被还原的产物,而单独使用硼氢化钠还原时却得到两个羰基同时被还原的产物。
Effect of some metal ions on selective reduction of benzoyl acetone was investigated using NaBH4 as a reducer. The results showed that 3-carbonyl was reduced with Cd^2+ addition, and 1,3-dicarbonyl were reduced without additive.
出处
《合成化学》
CAS
CSCD
2005年第5期458-460,共3页
Chinese Journal of Synthetic Chemistry
基金
广西自然科学基金资助项目(0135011)
广西教育厅科学基金资助项目