期刊文献+

HFCVD在硬质合金基体上沉积(110)&(100)金刚石薄膜 被引量:2

Deposit (110)&(100) Texture Diamond Films on Cemented Carbide Substrate by HFCVD
下载PDF
导出
摘要 以CH4和H2为反应气体,用热丝化学气相沉积(HFCVD)法在YG6(WC-6%Co)硬质合金基体上沉积了具有(110)和(100)织构的金刚石薄膜。用扫描电子显微镜、X射线衍射仪、压痕仪对样品进行了分析。结果表明:金刚石薄膜由约1μm大小立方金刚石晶粒组成,其形核密度大于2×108/cm2;(110)和(100)织构系数分别为0.59和0.033,压痕荷载为588N时附着性能良好。 (110)& (100) Texture diamond films were deposited on cemented carbide (WC-6%Co)substrate by Hot filament chemical vapor deposition (HFCVD), using the gas mixture of methane and hydrogen. The Surface morphology, texture and adhesion of the diamond films were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD) and Rockwell hardness tester respectively. The result shows that the diamond films are composed of cube crystals about 1μm and the density of nucleation is about 2×10^8/cm^2. The texture coefficient of (110)& (100)are 0.59 and 0.033 respectively, It shows good adhesion between diamond film and the substrate as the of indentation crack load is 588N.
出处 《硬质合金》 CAS 北大核心 2005年第4期208-211,共4页 Cemented Carbides
关键词 HFCVD 金刚石薄膜 形貌 织构 附着力 HFCVD diamond films, Surface morphology, texture, adhesion
  • 相关文献

参考文献12

  • 1Hideaki Itoh,SungSoo Lee,Kazuyoshi Sugyama,Hiroyasu Iwahara,Takahiro Tsutsumoto [J].Surface and Coatings Technology 112(1999)199-203.
  • 2C Faure,W Hanni,C Julia Schmutz,M Gervanoni.Diamond-coated tools[J].Diamond and Related Materials (1999) 8:830~833.
  • 3杨仕娥,马丙现,樊志琴,鲁占灵,姚宁,张兵临.WC-Co硬质合金基体上金刚石薄膜的附着机理研究[J].真空与低温,2004,10(1):39-42. 被引量:3
  • 4Ma Zhibin,Wang Jianhua,Wu Qingchong,Wang Chuanxin.Adhesion improvement of diamond films on cemented carbides with copper implant layer[J].Thin Solid Films 390 2001 104-106.
  • 5陈志红,余志明,许向阳,刘王平.甲烷浓度对金刚石薄膜织构的影响[J].金刚石与磨料磨具工程,2005,25(2):21-24. 被引量:8
  • 6王兵,冉均国,苟立.提高[100]织构金刚石薄膜相组成纯度的工艺方法[J].四川大学学报(工程科学版),2004,36(4):57-61. 被引量:7
  • 7安希忠,张禹,刘国权,秦湘阁,王辅忠,刘胜新.CVD金刚石膜{100}取向在改进化学反应模型下生长的原子尺度模拟[J].稀有金属材料与工程,2002,31(5):349-352. 被引量:4
  • 8J T Huang,W Y Yeh,J hwang,H Chang.Bias enhanced nucleation and bias textured growth of diamond on silicon (100) in hot filament chemical vapor deposition[J],Thin solid Films 315(1998)35-39.
  • 9Jinqi Miao,Jianhua Song,Yundon Xue,Yumei Tong,Weizhong Tang,Fanxiu Lu.Effect of a two-step pretreatment method on adhesion of CVD diamond coatings on cemented carbide substrates [J].Surface &Coatings Technology 187(2004)33~36.
  • 10Su Liu,Erqing Xie,Jianwei Sun,Changchun Ning,Yanfeng Jiang,A study on nano-nucleation and interface of diamond film prepared by hot filament assisted with radio frequency plasma [J].Materials letters 57(2003) 1662-1669.

二级参考文献23

  • 1张禹.化学气相沉积金刚石膜生长过程的计算机仿真及可视化[M].北京,2001..
  • 2SODERBERG S, GERENDAS A, SJOSTRAND M. Factors influencing the adhesion of diamond coatings on cutting tools [J]. Vacuum, 1990, 41(4-6):1 317-1 321.
  • 3SINGH R K, GILBERT D R, GERALD J F, et al. Engineered interfaces for adherent diamond coatings on large thermal-expansion coefficient mismatched substrate [J]. Science, 1996, 272:396-398.
  • 4TONSHOFF H K, MOHLFELD A, GEY C, et al. Mechanical pretreatment for improvement adhesion diamond coatings [J]. Surf Coat Technol, 1999, 116/119:440-446.
  • 5LIN C R, KUO C T, CHANG R M. Improvement in adhesion of diamond films on cemented WC substrate with Ti-Si interlayers [J], Diam Relat Mater, 1998, 7:1 628-1 632.
  • 6LOPEZ J M, BABAEV V G, KHVOSTOV V V, et al. Highly adherent diamond coatings deposited onto WC-Co cemented carbides via barrier interlayers [J], J Mater Res, 1998, 13(10):2 841-2 846.
  • 7SCHULTZ J, NARDIN M. Theories and mechanisms of adhesion, in adhesion promotion techniques (edited by Mittal K L, etal)[M]. New York:Marcel Dekker, Inc. , 1999.
  • 8FAN Q H, GRACIO J, PEREIRA E. Evaluation of residual stresses in chemical-vapor-deposited diamond films [J]. J Appl Phys, 2000, 87(6):2 880-2 884.
  • 9Leyendecker T,Lemmer O,Jurgens A,Esser S and Ebberink J.Industrial application of crystalline diamond-coated tools [ J ].Surface and Coating Technology, 1991,48 (3) :253 ~ 260.
  • 10Park B S,Baik Y J, Lee K Y,Eun K Y and Kim D H. Behavior of cobalt binder phase during diamond deposition on WC-Co substrate[ J]. Diamond and Related. Materials, 1995,2 ( 5 ):910 ~917.

共引文献18

同被引文献27

  • 1陈响明,王社权,易丹青.铸铁加工专用切削刀片的研制与应用[J].工具技术,2005,39(5):56-59. 被引量:7
  • 2黄元盛,刘宏伟,邱万奇,罗承萍,陈灵.CVD金刚石的晶体形态及界面位向关系[J].材料导报,2007,21(1):30-32. 被引量:3
  • 3张静,李昆,陈响明.硬质合金刀片α-Al_2O_3涂层研究[J].硬质合金,2007,24(1):9-12. 被引量:5
  • 4Lee M,Koeh E F,Hale T E.A study of the coating substrate interface layer of an Al2O3coated cemented carbide cutting tool[J].Int.J of Refractory Metal&Hard Materials,1996,14:335-343.
  • 5Kathrein M,Sohintlmeister W,Wallgram W,Sohleinkofer U.Doped CVD Al2O3coatings for high performance cutting tools[J].Surface and Coatings Technology,2003,163-164:181-188.
  • 6Chen Xiangming,Liu Huiqun,Guo Qinghua,et al.Oxidation behavior of WC-Co hard metal with designed multilayer coatings by CVD[J].International Journal of Refractory Metals and Hard Materials,2012,31:171-178.
  • 7Liu Wangping,Chen Xiangming,Wei Quiping.The influence of Ti Al CNO layer on the microstructure and properties of Al2O3coating[C].18th Plansee Seminar,HM 142/1.
  • 8Ruppi S.Enhanced performance ofα-Al2O3coatings by control of crystal orientation[J].Surface and Coatings Technology,2008,202(17):4257-4269.
  • 9Ruppi S,Larsson A,Flink A.Nanoindentation hardness,texture and microstructure ofα-Al2O3andκ-Al2O3coatings[J].Thin Solid Films,2008,516:5959-5966.
  • 10Ruppi S.Deposition,microstructure and properties of texture-controlled CVDα-Al2O3coatings[J].International Journal of Refractory Metals and Hard Materials,2005,23:306-316.

引证文献2

二级引证文献11

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部