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NiO/AC非对称超级电容器的研究 被引量:6

Study on NiO/AC Asymmetric Supercapacitors
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摘要 通过热处理球形Ni(OH)2得到NiO粉末,将其作为正极与活性炭(AC)负极组装成非对称超级电容器,用恒流充放电测试分析了超级电容器的电容特性。讨论了正负极活性物质比例、充放电电流和热处理时间对超级电容器比电容量、内阻的影响。结果表明:正负极活性物质比为1∶3,工作电流密度为200 mA/g,当Ni(OH)2的热处理时间为2h,充电电压为1.3 V时,超级电容器的双电极比电容量可达71.5 F/g。 The NiO powder is obtained by the heat treatment of spherical Ni(OH)_2.Asymmetrical supercapacitors are assembled using NiO as the positive electrodes and AC as the negative electrodes and tested through the galvanostantic charge/discharge measurements.The effect of the mass ratio of positive electrode and negative electrode,charge/discharge current density and annealing time on specific capacitance,interior resistance was discussed.It is proved that the specific capacitance of the supercapacitor reaches 71.5 F/g under the mass ratio of 1:3,the charge/discharge current density of 200mA/g,the annealing time of 2 hours and charge voltage of 1.3V.
出处 《西华大学学报(自然科学版)》 CAS 2006年第1期6-7,13,共3页 Journal of Xihua University:Natural Science Edition
基金 国家自然科学基金资助项目(编号:50307009) 西华大学人才基金资助项目(0321143)
关键词 NIO 超级电容器 非对称 nickel oxide supercapacitor assymmetrical
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参考文献9

  • 1B E Conway. Transition from super capacitor to “battery” behavior in electrochemical energy storage [J]. Electrochem Soc., 1991,138(6) : 1539-1548.
  • 2王晓峰,孔祥华,刘庆国,解晶莹.氧化镍超电容器的研究[J].电子元件与材料,2000,19(5):26-28. 被引量:15
  • 3王晓峰,孔祥华.新型氧化镍超电容器电极材料的研究[J].无机材料学报,2001,16(5):815-820. 被引量:20
  • 4王晓峰,孔祥华,刘庆国,解晶莹.氧化镍超电容器的研究[J].电源技术,2001,25(3):219-222. 被引量:11
  • 5K C Liu, M A Anderson. Porous nickel oxide/nickel films forelectrochemical capacitors [J]. Electroehem. Soc., 1996, 143(1) : 124-130.
  • 6K C Liu, M A Anderson. Proceedings of the Symposium on Electrochemical Capacitors[J]. Electr ochem Soc., 1995 : 68-70.
  • 7V Srinivasan, WJ Welder. An electroehemieal route for making porous nickel oxide electrochemieal capacitors [J]. Electrochem. Sot.,1997,144(1) :210-217.
  • 8Nan K W,Kim K B. A study of the NiOx electrode via electrochemical route for super capacitor applications and their charge storage mechanism[J]. Electrochem Soc., 2002,149 ( 3 ) : 335-337.
  • 9于维平,杨晓萍,王光明.电沉积-烧结制备掺杂C,Co的纳米NiO电极及其电容性能[J].科学通报,2004,49(11):1052-1055. 被引量:6

二级参考文献26

  • 1何业东,Stott,FH.氧化物薄膜促使镍铬合金高温选择氧化的研究[J].中国有色金属学报,1995,5(3):48-53. 被引量:5
  • 2Conway B E. Transition from "Supercapacitor"to "Battery" behavior in electrochemical energy storage. J Electrochem Soc, 1991,138(6): 1539~1548
  • 3Sarangpani S, Tilak B V, Chen C P. Materials for electrochemical capacitors. J Electrochem Soc, 1996, 143(11): 3791
  • 4Liu K C, Anderson M A. Porous nickel oxide/nickel films for electrochemical capacitors. J Electrschem Soc, 1996, 143(1): 124~130
  • 5Liu K C, Anderson M A. Porous nickel oxide films for electrochemical capacitors. In: Delnick F M, Tomkiewicz M, ed. Proceeding of the Symposium on Electrochemical Capacitors. Pittsburgh: Materials Research Society, 1995.68
  • 6Srinivasan V, Weidner J W. An electrochemical route for making porous nickel oxide electrochemical capacitors. J Eelctrochem Soc, 1997, 144(8): L210~L213
  • 7Nam K W, Kim K B. A study of the NiOx electrode via electrochemical route for supercapacitor applications and their charge storage mechanism. J Electrochem Soc, 2002, 149(3): A346~354
  • 8He Yedong, Stott F H. The selective oxidation of Ni-15%Cr and Ni-10%Cr alloys promoted by surface-aplied thin oxide films.Corrosion Science, 1994, 36(11): 1869~1884
  • 9He Yedong, Stott F H. The effect of thin surface applied oxide coating films on the selective oxidation of alloys. Corrosion Science, 1996, 38(11): 1853~1868
  • 10Chuan Lin,J Electrochem Soc,1998年,145卷,12期,4097页

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