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Troubleshooting and Optimization of High-Strength Inhibitory Chemical Wastewater Treatment Process

Troubleshooting and Optimization of High-Strength Inhibitory Chemical Wastewater Treatment Process
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摘要 Wastewaters from the chemical industry are usually of high-strength and may contain minor inhibitory and recalcitrant organics that are at times not readily identifiable. This paper describes the experience of a biological waste water treatment plant (WWTP) processing a COD concentration of 43000 mg·L^-1 wastewater from an oxochemical manufacturing plant. Stage improvements of the plant process by dilution of the inhibitory influent using other chemical wastewater streams resulting in a synergistic process effect, and removal of inhibitory organics by phase separation via acidification, effectively achieved process optimization producing a high quality effluent. In particular, the COD removal efficiency of granular sludge based anaerobic reactors increased from 56% to 90%. The final effluent COD decreased from 250mg·L^-1 to 50mg·L^-1, consistently meeting the COD concentration of 100 mg·L^-1 regulatory discharge limit. The success of the process enhancements supports the hypothesis that long-chain quaternary carboxylic acids act as substrate inhibitors in the biological process. 从化学工业的废水通常具有高张力并且可以包含是的次要的禁止、不顺从的 organics 有时,不乐意地, identifiable.Thispaper 描述处理 43000 mg 中心点L~的 CODconcentration 的生物废水处理植物( WWTP )的经验(从含氧化学药品的 manufacturingplant.Stage 的-1)废水改进由导致 synergistic 进程的化学废水流完成的禁止的流入的使用其它的冲淡的植物过程,和由经由使发酸的析相作用的禁止的 organics 的移动,生产一条高质量的自河的有效地完成的进程优化。特别地,粒状淤渣的货到付款移动效率基于从 56% ~ 90%.The 期末考试自河货到付款增加的厌氧的反应堆从 250mg 中心点 L~ 减少了(-1) to50mg 中心点 L^(-1),consistently 遇见 l00 mg 中心点 L~ 的 COD 集中(-1)regulatory 分泌物限制。进程改进的成功在生物进程作为底层禁止者支持假设 thatlong 链 quaternary 羧酸行为。
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2005年第6期800-808,共9页 中国化学工程学报(英文版)
关键词 operational experience waste water treatment plant (WVCTP) granular sludge chemical wastewater INHIBITORY RECALCITRANT long-chain quaternary carboxylic acids 高浓度有毒化工废水 废水处理工艺 诊治 优化 粒状淤渣 长链四羧基酸
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参考文献5

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