摘要
报道了合成环氧化合物的新方法．于水存在下１，３－二溴－５，５－二甲基已内酰脲与直链脂肪族、脂环族、芳香族等含活泼双键化合物进行次溴酸化反应生成溴醇、在碱作用下消除溴化氢得环氧产物，总收率７３％～８６％．
A novel method for the synthesis of epoxide was reported. The aliphatic, alicyclic andaromatic hydrocarbons containing active double bonds can be hypobrominated by using 1,3-dibromu-5,5-dimethylhydartoin in the presence of water to give bromhydrios(4) from which hydrogen bromide was eliminated by base cyclization to give the corresponding epoxide in 73%～86% overall yield.
出处
《湖北大学学报（自然科学版）》
CAS
1996年第1期64-66,共3页
Journal of Hubei University：Natural Science
