摘要
在甲苯溶剂中用“一锅反应法”，以４７．６％～９２．０％的收率合成了１４个通式为［ＲＯ（２－ＣＨ３ＳＣ６Ｈ４Ｏ）Ｐ（Ｏ）ＮＨＲ１］新的磷酰胺酯化合物，用元素分析、ＩＲ和ＮＭＲ进行了表征，生物试验发现４个目标化合物［４ａ：Ｒ＝Ｍｅ，Ｒ１＝Ｈ；４ｂ：Ｒ＝Ｍｅ，Ｒ１＝ｎＰｒ，４ｇ：Ｒ＝Ｍｅ，Ｒ１＝ｉＢｕ；４ｈ：Ｒ＝Ｅｔ，Ｒ１＝Ｈ］在０．０２５％的浓度下杀蚜虫的死亡率为９０．７％～９８．９％．
Fourteen new alkoxyl -2-methylthiophenoxy phosphoramidates were synthesized by one-pot reaction using toluene as solvent in 47. 6%～92. 0% yields.Their structures were characterized by elemental analysis, IR, and NMR spectroscopy. Their insecticidal activities were tested. Among them four compounds showed remarkable activities by giving 90. 7%～98. 9% mortality for aphid at 0. 025%.
出处
《华中师范大学学报（自然科学版）》
CAS
CSCD
1996年第2期177-181,共5页
Journal of Central China Normal University：Natural Sciences
基金
湖北省自然科学基金
关键词
有机磷化合
磷酰胺酯
杀虫活性
生物活性
organophosphorous compound
phosphormidate
synthesis
insecticidal activity
