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Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions 被引量:1

Thiol-functionalized MCM-48: an Effective Absorbent of Mercury Ions
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摘要 Mercaptopropyl groups were grafted onto the pore walls of mesoporous molecular sieves MCM-48. The pore structures were characterized by powder X-ray diffraction and N2 adsorption analYSiS. Elemental analysis confirmed that the material with high organic moiety (2.2 mmol/g) had been obtained. ^13C MAS NMR verified the tethered organic groups. The thiol-functionalized MCM-48 showed effective capture of mercury ions, and all of the organic ligands were accessible for the binding of mercury ions. Mercaptopropyl groups were grafted onto the pore walls of mesoporous molecular sieves MCM-48. The pore structures were characterized by powder X-ray diffraction and N2 adsorption analYSiS. Elemental analysis confirmed that the material with high organic moiety (2.2 mmol/g) had been obtained. ^13C MAS NMR verified the tethered organic groups. The thiol-functionalized MCM-48 showed effective capture of mercury ions, and all of the organic ligands were accessible for the binding of mercury ions.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2006年第2期221-224,共4页 中国化学快报(英文版)
基金 the Science Foundation of South-Central University of Nationalities (yzz 04001).
关键词 Mercaptopropyl MCM-48 ABSORBENT mercury ions. Mercaptopropyl, MCM-48, absorbent, mercury ions.
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同被引文献8

  • 1金忠秀,童红武,雍国平,盛良全,刘清亮,刘少民.Ce-MCM-48介孔分子筛的合成、表征和催化性能[J].Chinese Journal of Chemical Physics,2005,18(6):1057-1061. 被引量:14
  • 2冯尚华,何国芳,杜建全,李衍飞.非水介质中合成介孔分子筛MCM-41[J].化学学报,2007,65(6):566-570. 被引量:7
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