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溶胶-凝胶法制备用于CO_2气氛下乙苯脱氢反应的高活性Cr_2O_3-SiO_2催化剂 被引量:8

Preparation of Highly Active Cr_2O_3-SiO_2 Catalyst by Sol-Gel Method for Ethylbenzene Dehydrogenation in the Presence of CO_2
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摘要 The Cr2O3-SiO ? catalyst was prepared by a sol-gel method. It displays two times higher catalytic activity for the dehydrogenation of ethylbenzene in the presence of CO2 than the regular SiO2-supported chromia catalyst.The higher amount of Cr 6+ present in the former catalyst accounts for its superior catalytic performance in the dehydrogenation reaction. The Cr203-SiO2 catalyst was prepared by a sol-gel method. It displays two times higher catalytic activity for the dehydrogenation of ethylbenzene in the presence of CO2 than the regular SiO2-supported chromia catalyst. The higher amount of Cr^6 + present in the former catalyst accounts for its superior catalytic performance in the dehydrogenation reaction.
出处 《催化学报》 SCIE CAS CSCD 北大核心 2006年第1期4-6,共3页
基金 国家重点基础研究发展规划(2000077507) 上海市重大基础研究(03DJ14004) 国家自然科学基金(20303004) 上海市自然科学基金(03ZR14013) 上海石油化工研究院资助项目.
关键词 氧化铬 氧化硅 溶胶-凝胶法 乙苯 脱氢 苯乙烯 二氧化碳 chromia silica sol-gel method ethylbenzene dehydrogenation styrene carbon dioxide
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参考文献9

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