摘要
Batch tests were carried out to study the possibility of hydrogen production from alkali-pre- treated sludge without seed and the pH dependency of hydrogen fermentation from alkali-pretreated sludge. Experimental results showed that the sewage sludge with alkali-pretreatment could be successfully applied to biologically producing hydrogen without seed and extra-feed. The results also showed that the initial pH value of sewage sludge was an impor-tant factor throughout the hydrogen fermentation of alkali-pretreated sludge. The maximum hydrogen yield was obtained at initial pH value of 11.0 (14.4 mL·g VS-1). The hydrogen yield of alkali-pretreated sludge at alkaline initial pH value was much higher than that of acidic or neutral initial pH value. The op-timal pH value of hydrogen production from alkali- pretreated sludge was approximately 9.5. The con-sumption of hydrogen could be inhibited when the pH value of sludge was above 8.5. The change of hy-drogen yield at various initial pH values was similar to that of sludge SCOD. The change of sludge pH value was slow and acetate was the major component of volatile fatty acids produced in the process of hy-drogen production. The yield and the constitution of volatile fatty acids were sensitive to the initial pH value.
Batch tests were carried out to study the possibility of hydrogen production from alkali-pretreated sludge without seed and the pH dependency of hydrogen fermentation from alkali-pretreated sludge. Experimental results showed that the sewage sludge with alkali-pretreatment could be successfully applied to biologically producing hydrogen without seed and extra-feed. The results also showed that the initial pH value of sewage sludge was an important factor throughout the hydrogen fermentation of alkali-pretreated sludge. The maximum hydrogen yield was obtained at initial pH value of 11.0 （14.4 mL.g VS^-1）. The hydrogen yield of alkalipretreated sludge at alkaline initial pH value was much higher than that of acidic or neutral initial pH value. The optimal pH value of hydrogen production from alkalipretreated sludge was approximately 9.5. The consumption of hydrogen could be inhibited when the pH value of sludge was above 8.5. The change of hydrogen yield at various initial pH values was similar to that of sludge SCOD. The change of sludge pH value was slow and acetate was the major component of volatile fatty acids produced in the process of hydrogen production. The yield and the constitution of volatile fatty acids were sensitive to the initial pH value.
关键词
碱预处理
厌氧发酵
制氢
污泥
PH值
废水处理
alkali-pretreatment, anaerobic fermentation, hydrogen production, sewage sludge, pH value.
