摘要
本文介绍了氯化溴(BrCl)的应用领域及合成工艺。通过对已有工艺的比较与理论分析,可采用低温液相合成。小试结果表明:在所研究的温度范围内,适宜的合成温度在-15℃^-17℃之间,产品中溴的质量分数为69.29%(理论值为69.27%);在四氯化碳中,吸光度达到最大值时对应的波长为380 nm,与文献值吻合。100 t/a中试亦取得了预期的结果。与已有工艺相比:本工艺简化了流程,易于操作和控制。中试的成功为产业化奠定了基础。
In this paper, application and synthesis technology of bromine chloride（ BrC1）are introduced. Based on other technologies and theory analysis, low temperature-liquid synthesis technology is counfirmed. The result shows that the optimal temperature is between - 15 ℃ and - 17 ℃,weight content of Br in BrCl is 69.26% （Theoretical value 69.27%）. Dissolved in CCl4, the maximal absorbance wave of BrCl is 380 nm in UV spectrophotometer, the value is in accordance with referenced value. Pilot plant of 100 t/a also makes anticipativc result. Compared with other technologies, this process has many advantage such as simple process, easy operation and controlling. Pilot plant gives the foundation for the future commercialization.
出处
《化学工业与工程》
CAS
2006年第2期178-180,共3页
Chemical Industry and Engineering
基金
2003天津市科技攻关培育项目(033103711B)
关键词
氯化溴
中试
低温
合成工艺
bromine chloride
pilot scale
low temperature
synthesis technology
