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载铜5A分子筛在汽油模拟体系中脱硫性能的研究 被引量:17

Desulfurization of model gasoline by 5A molecular sieves loaded with Cu^(2+)
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摘要 The desulfurization of model gasoline by 5A molecular sieves loaded with Cu2+ was studied.Several factors which influence the desulfurization capability,including temperature,Cu2+ loading,baking temperature,as well as the ethanethiol concentration were investigated.In the range of adsorption temperature of 20℃45℃,it was found that the sorption capacity of ethanethiol on 5A molecular sieves loaded with Cu2+ increases with the temperature increasing.The desulfurization is enhanced by increasing the Cu2+ loading and the best result is obtained at the Cu2+ loading of 0.16mol/L.Baking of the sorbent can also improve the desulfurization capability,and the optimum baking temperature is 300℃.Two methods of the sorbent regeneration were compared in the experiment,the regeneration by baking is better than that by alcohol washing. The desulfurization of model gasoline by 5A molecular sieves loaded with Cu^2+ was studied. Several factors which influence the desulfurization capability, including temperature, Cu^2+ loading, baking temperature, as well as the ethanethiol concentration were investigated. In the range of adsorption temperature of 20 ℃ - 45 ℃ , it was found that the sorption capacity of ethanethiol on 5A molecular sieves loaded with CuE+ increases with the temperature increasing. The desulfurization is enhanced by increasing the Cu^2+ loading and the best result is obtained at the Cu^2+ loading of 0.16 mol/L. Baking of the sorbent can also improve the desulfurization capability, and the optimum baking temperature is 300 ℃ . Two methods of the sorbent regeneration were comoared in the exoeriment,the regeneration by baking is better than that by alcohol washing.
出处 《燃料化学学报》 EI CAS CSCD 北大核心 2006年第1期117-119,共3页 Journal of Fuel Chemistry and Technology
基金 国家自然科学基金(20436030) 江苏省重点实验室开放课题(KJS03017)
关键词 汽油 硫醇 脱硫 吸附剂 gasoline ethanethiol desulfurization sorption 5A molecular sieves
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