摘要
Two New heteropoly molydovanadateselenite complexes with formulas[Se2Mo2V4O24]8-and[Se2Mo3V3O24]7- were reported for the first time.These complexes were isolated at pH=2.It is proved that the ratios of Mo and V in materidal influence the constitution of complexes.These complexes were characterized by elemental analysis,IR,UV,XRD,molar conductance and TG-DTA.It is deduced that these complexes may have the basic skeleton of X2M6 structure.
Two New heteropoly molydovanadateselenite complexes with formulas[ Se2Mo2V4O24]^8- and [ Se2Mo3V3O24]^7- were reported for the first time. These complexes were isolated at pH = 2. It is proved that the ratios of Mo and V in materidal influence the constitution of complexes. These complexes were characterized by elemental analysis, IR, UV, XRD, molar conductance and TGDTA. It is deduced that these complexes may have the basic skeleton of X2M6 structure.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2006年第4期403-405,共3页
Chemical Research and Application
基金
国家自然科学基金资助(40301050)
关键词
硒钼钒三元杂多配合物
合成与表征
X2M6的结构
Heteropoly molydovanadateselenit Complexes
Characterzation
Synthesis
X2M6 structure
