摘要
合成了2,3,7,8,12,13,17,18八苄硫基四氮杂卟啉的Co(Ⅱ)、Zn(Ⅱ)配合物,对其进行了元素分析、紫外可见光谱和红外光谱表征,并考察了配体及配合物的循环伏安性质,初步讨论了三个化合物电氧化还原的机理.
The cobalt ( Ⅱ ) and zinc ( Ⅱ ) complexes of 2, 3,7,8, 12, 13, 17,18 - octakis (benzylthio) tetraazaporphyrin were synthesized and characterized by elemental analysis,UV and IR spectra. The redox behaviours of the ligand and its two complexes were investigated by cyclic voltammetry. Possible mechanism of the electrode reaction has been proposed.
出处
《武汉化工学院学报》
2006年第2期1-4,共4页
Journal of Wuhan Institute of Chemical Technology
基金
国家自然科学基金项目(No.20471045)
湖北省自然科学基金项目(No.2005ABA021)
湖北省教育厅重点项目(No.D200515004)
关键词
四氮杂卟啉
合成
电化学
tetraazaporphyrin
synthesis
electrochemistry