摘要
以硫酸钛、尿素为主要原料,采用均相沉淀法对α-Al2O3微滤复合膜进行了纳米TiO2 的涂覆改性,着重考察了反应温度、反应物浓度与涂覆次数对改性作用的影响．实验结果表明,制备的TiO2改性涂层光滑致密,晶粒尺寸为10-15nm,使改性后的Al2O3微滤复合膜水通量提高了19％以上．用TEM、Zeta电位分析手段对改性涂层进行了测试分析,探讨了改性的机理．
For the modification of α-Al2O3 microfiltration membrane, the nano-crystalline TiO2 coating was obtained by a homogeneous precipitation method using titanium sulfate and urea as raw materials. The effects of reaction temperature, reactant concentration and coating times on the modification of the membrane were investigated systematically. The micro-structure of nano- crystalline TiO2 coating and its modifying mechanism were also studied by means of TEM, Zeta electric potential analyzer etc. The results show that nano-crystalline TiO2 modifying coating composed of 10-15nm grains is smooth and dense, and the water flux of the modified membrane is increased by more than 19% over the membrane before modification.
出处
《无机材料学报》
SCIE
EI
CAS
CSCD
北大核心
2006年第3期725-730,共6页
Journal of Inorganic Materials
基金
国家"973"预研项目(2004CCA07500)
关键词
均相沉淀法
微滤膜
氧化钛
改性涂层
homogeneous precipitation method
microfiltration membrane
titanium oxide
modifying coating
