摘要
以市售β紫罗兰酮为起始物,经臭氧化制得环柠檬醛,然后经Darzen缩合制得环高柠檬醛。采用自制的催化剂一步将环高柠檬醛转化成二氢猕猴桃内酯(9氧杂1,5,5三甲基双环〔4,3,0〕壬6烯8酮),产物经MS。
Dihydroactinidiolide was synthesized by one step reaction from cyclohomocitral which was prepared from β ionone by ozonization and Darzen′s reaction.The title compound was identified by MP,IR,MS and elemental analysis. \ \
出处
《精细化工》
CAS
CSCD
1996年第4期20-21,共2页
Fine Chemicals