期刊文献+

纳米ZnO的制备及其光催化活性研究 被引量:2

Preparation of nanocrystal ZnO particles and its photocatalyse performance
下载PDF
导出
摘要 采用直接沉淀法、微乳法及乙醇锌合成法制备了不同晶粒尺寸的ZnO纳米粒子,用XRD和TEM技术对样品进行表征.取粒径最小的纳米ZnO作光催化剂,以太阳光为光源,并以光催化降解罗丹明-B为模型反应,探讨用纳米ZnO光催化降解有机污染物的途径. Nanocrystal ZnO particles with different size are prepared respectively by direct precipitation,microemulsion and sol-gel methods. The as-prepared samples are also characterized by techniques such as XRD and TEM. Using solar energy,the smallest ZnO nanoparticle as a photocatalyst,effective degradation of rhodamine B model pollutant is observed. Then in this way nanocrystal ZnO photocatalysis degradation of other organic pollutants is also investigated.
出处 《内蒙古师范大学学报(自然科学汉文版)》 CAS 2006年第2期215-218,共4页 Journal of Inner Mongolia Normal University(Natural Science Edition)
基金 国家教育部科学技术研究重点项目(204027) 内蒙古高等学校科学研究项目(NJ02037) 内蒙古师范大学科研基金项目(YJS005004)
关键词 纳米ZNO 制备 太阳光 光催化 nanocrystal ZnO particles preparation daylight photocatalysis
  • 相关文献

参考文献7

二级参考文献65

  • 1金建国,张文丽,邱继军,邸云萍.TiO_2光催化剂的应用及其关键技术[J].陶瓷学报,2001,22(4):276-279. 被引量:8
  • 2徐甲强,朱文会,陈源.ZnO气敏陶瓷的制备与气敏性能研究[J].功能材料,1993,24(1):30-33. 被引量:23
  • 3王宝辉,王德军,崔毅,李铁津.CdS超微粒子薄膜电极的光电化学特性[J].高等学校化学学报,1995,16(10):1610-1613. 被引量:22
  • 4陈士夫,赵梦月,陶跃式,梁新.玻璃纤维附载TiO_2光催化降解有机磷农药[J].环境科学,1996,17(4):33-35. 被引量:123
  • 5刘俊峰.中小型印染厂废水的处理方法[J].工业水处理,1996,16(6):8-10. 被引量:26
  • 6Berry R J, Mueller M R. Photocatalytic Decomposition of Crude Oil Slicks Using TiO2 on a Floating Substrate[J]. Microchemical Journal, 1994, 50 : 28- 32.
  • 7Cunningham J, Srijaranal S. Isotope-Effect Evidence for Hydroxyl Radical Involvement in Alcohol Photo-Oxidation Sensitized by TiO2 in Aqueous Suspension[J ]. JPPAC, 1988, 43: 329-335.
  • 8Zhao J C, Octa H, Hidaka H. Photodegradation of Surfactants X Comparison of the Photooxidation of Thearomatic Moieties in Sodium Do-Decylbenzene Sulphonate and in Sodium Phenyldodecyl Sulphonate at TiO2-H2O Interfaces[J]. JPPAC, 1992, 69:251- 256.
  • 9Augustynaki. Characterization of Electrod-Eposited TiO2 Films[J]. J Electrochim Acta, 1993, 38: 43-47.
  • 10Scalafani A,Hermann J M.Comparison of the Photoelectronic and Photocatalytic Activities of Various Anatase and Rutile Forms of Titania in Pure Liquid Organic Phases and in Aqneous Solutions[J].J Phys Chem,1996,100:13655—13661.

共引文献192

同被引文献20

  • 1洪若瑜,徐丽萍,任志强,李忻,李洪钟.纳米氧化锌的制备及其光催化活性研究[J].化工环保,2005,25(3):231-234. 被引量:19
  • 2朱亦仁,解恒参,姚坚,戴桂元.ZnO粉体的制备及在光催化法处理造纸废水中的应用[J].南京工业大学学报(自然科学版),2005,27(3):21-25. 被引量:17
  • 3王贤亲,张国亮,张凤宝.Cu^(2+)/TiO_2-SiO_2催化剂的制备及其光催化降解气相间二甲苯的性能[J].石油化工,2006,35(3):277-280. 被引量:6
  • 4叶红勇,赖宏伟,吴淑杰,崔湘浩,阚秋斌,榆正根.常温直接沉淀法制备ZnO纳米棒[J].高等学校化学学报,2007,28(2):312-315. 被引量:19
  • 5[6]ANDREAS T,GUNNAR G,DENNIS P.Kinetics and particle formation mechanism of zinc oxide particles in polymer-controlled precipitation from aqueous solution[J].Langmuir,2002,18(11):4488-4494.
  • 6[7]NI Yong-hong,WEI Xian-wen,HONG Jian-ming,et al.Hydrothermal preparation and optical properties of ZnO nanorods[J].Mater Sci Eng B,2005,121(1-2):42-47.
  • 7[8]JOO J,KWON S G,YU J H,et al.Synthesis of ZnO nanocrystals with cone,hexagonal cone,and rod shapes via non-hydrolytic ester elimination sol-gel reactions ester flimination sol-gel reactions[J].Adv Mater,2005,17(15):1873-1877.
  • 8[9]WANG G Z,WANG Y,YAU M Y,et al.Synthesis of ZnO hexagonal columnar pins by chemical vapor deposition[J].Mater Lett,2005,59(29-30):3870-3875.
  • 9[10]ELLIS B,KEIM W,WASSERSCHEID P.Linear dimerization of but-1-ene in biphasic mode using buffered chloraluminate ionic liquid solvents[J].Chem Comm,1999(4):337-338.
  • 10[11]THOMAS W.Room-temperature ionic liquids solvents for synthesis and catalysis[J].Chem Rev,1999,99(8):2071-2083.

引证文献2

二级引证文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部