摘要
含间苯基聚芳醚酮的合成与性能研究林权，张万金，吴忠文，尹玖梅（吉林大学化学系，长春，１３００２１）（中国科学院长春应用化学研究所）关键词聚芳醚酮，间苯基，熔点，结晶度聚芳醚酮作为一类耐高温特种工程塑料，由于具有优异的热、电、机械性能，已被广泛应用于电...
A series of poly(aryl ether ketone)s containing meta-phenyl links are synthesized,DSC and wide-angle X-ray scattering,etc.are used to study the general properties of the polymers.With the increasing of meta linkage monomer percentage,the melting temperature decreases sharply at first,then rises steadily,the glass transition point keeps a stable value,and crystallinity and crystallizing rate are reduced.A part of amorphous film of the polymer is annealed at different temperatures. DSC scan shows that besides Tm,a new melting peak( T'm)at low temperature appears.And with heat treating temperature rising,T'm shifts to high temperature, and Tm keeps a stable value.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1996年第8期1322-1324,共3页
Chemical Journal of Chinese Universities
基金
国家"八.五"项目
"863"项目
关键词
聚芳醚酮
间苯基
熔点
结晶度
Poly(aryl ether ketone)s, meta-Phenyl links,Melting temperature,Crystallinity
