期刊文献+

石灰石煅烧过程中产物CaO孔隙分布变化研究 被引量:8

A Study of the Change in Pore Distribution of CaO Produced in the Process of Limestone Calcination
下载PDF
导出
摘要 首次以孔径长度分布函数为基础,结合比表面积和孔隙率等参数,建立了石灰石煅烧过程中产物CaO孔隙孔径分布模型。并结合实验结果,对CaO孔的分布特性及其受烧结影响而不断演化的过程进行了模拟研究。研究时将0~50A、50~200A、200A以上这3种孔径范围的孔进行了重点分段分析,计算表明3个孔径范围(0~50A、50~200A、200A以上)的孔在不同的煅烧阶段对比表面积的贡献是不断发生变化的。在此基础上提出了最佳煅烧率的概念。最佳煅烧率随着煅烧温度的提高而向后推迟。 Based on the distribution function of pore lengths and in combination with such parameters as specific surface area and porosity etc.A pore diameter distribution model was established for the first time for CaO product generated in the process of limestone calcination.In conjunction with experimental results,a simulation study was conducted of CaO pore distribution characteristics and their continuously evolving process whenbeing subjected to the influence of sintering.In the course of the study,a section-by-section analysis has been made with emphasis on the pores with a diameter in the range of 0~50 ?,50~200 ? and over 200 ?.The calculation results indicate that the contribution from the pores in three ranges of pore diameters(0~50 ?,50~200 ? and over 200 ?) to specific surface areas in different calcination stages undergoes a continuous change.On this basis,a concept of optimum calcination rate is proposed,which will take place later with an increase in calcination temperature.
出处 《热能动力工程》 CAS CSCD 北大核心 2006年第4期370-372,共3页 Journal of Engineering for Thermal Energy and Power
基金 电力行业青年科技促进费基金资助项目(SPQKJ02-07) 华北电力大学博士学位基金资助项目(09310015)
关键词 石灰石 CaO煅烧 孔径发布 最佳煅烧率 limestone,CaO,calcination,pore diameter distribution,optimum calcination rate
  • 相关文献

参考文献1

二级参考文献12

  • 1Farin, D, Avnir, D, "The fractal nature of molecule-surface interactions and reactions", In: The Fractal Approach to Heterogeneous Chemistry, Avnir, D., Ed., John Wiley & Sons, New York (1989).
  • 2Kopelman, R, "Diffusion-controlled reaction kinetics", In: The Fractal Approach to Heterogeneous Chemistry, Avnir, D, Ed, John Wiley & Sons, New York (1989).
  • 3Guo, X Y, Keil, F J, "Kinetics of N2O catalytic decomposition over three-dimensional fractals", Chem Phys Lett,330, 410-416 (2000).
  • 4Rothschild, W G, Fractals in Chemistry, John Wiley & Sons, New York (1998).
  • 5Sheintuch, M, Brandon, S, "Deterministic approaches to problems of diffusion-reaction and adsorption in a fractal porous catalyst", Chem Eng Sci, 44, 69 (1989).
  • 6Coppens, M O, Froment, G F, "Diffusion and reaction ina fractal catalyst pore", Chem Eng Sci, 40, 69 (1994).
  • 7Giona, M, Schwalm, W A, Adrover, A, Schwalm, M K,"First-order kinetics in fractal catalyst: Renormalization analysis of effectiveness factor", Chem Eng Sci, 51, 2273(1996).
  • 8Mougin, P, Pons, M, Villermaux, J, "Reaction and diffusion at an artificial fractal interface: evidence for a new diffusion regime", Chem Eng Sci, 51 (10), 2293-2302(1996).
  • 9Gavrilov, C, Sheintuch, M, "Reaction rates in fractalvs. uniform catalysts with linear and nonlinear kinetics", AIChE J, 43 (7), 1691-1699 (1997).
  • 10Sheintuch, M, "On the intermediate asymptote of diffusion-limited reactions in a fractal porous catalyst", Chem Eng Sci, 55, 615-624 (2000).

共引文献2

同被引文献55

引证文献8

二级引证文献13

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部