摘要
以二茂铁甲氨基醇与氯硅烷反应，合成了１２种二茂铁甲氨基烷氧基硅烷。研究了该化合物的合成方法、水敏感性与结构的关系，并由元素分析、红外光谱和核磁共振氢谱鉴定了化合物的结构。
The reaction between ferrocenylmethylaminoalcohols and chlorosilanes gave 12 compounds of ferrocenylmethylaminoalkoxy silanes in one-step method and in relatively good yield.The synthetic method and relationship between the water sensitivity and structures of the compounds were investigated.The experimental results show that both of the aminoalcohols FcCH2NHCH(R')CH(R″)OH(Fc=C5H5FeC5H4,R'=H,C2H5;R″=H,CH3)and chlorosilanes R(CH3)2SCl(R=CH3,C2H5,n-C3H7,n-C4H9)have influnce on the reaction.The more bulky R,R'and R″,the smaller the reaction rate.The title compounds FcCH2NHCH(R')CH(R″)OSi(CH3)2R,are relatively sensitive to water.The more bulky R,R'and R″,the more stable the compound to water.The structures were characterized by elementary analysis,IR and 1H NMR.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1996年第11期1725-1728,共4页
Chemical Journal of Chinese Universities
基金
内蒙古自治区自然科学基金
关键词
二茂铁甲氨基
烷氧基
硅烷
二茂铁甲氨基醇
合成
Ferrocenylmethylaminoalkoxy silane,Ferrocenylmethylaminoalcohol,Water sensitivity
