摘要
The complex Ag(L)NO3 (1) L=1,5-bis(imidazol-1-yl)pentane was synthesized in ethanol and water, and characterized by elemental analysis and X-ray crystal structural analysis. The result shows that the complex crystallizes in monoclinic, space group P21 / c with a=0.695 7(4) nm, b=0.988 7(4) nm, c=1.974 8(7) nm, β=91.934(19)°, V=1.357 5(10) nm3, Z=4, Dcalc=1.831 g·cm-3, F(000)=752, μ=1.50 cm-1, the final R=0.036 6, wR=0.091 0. The coordination environment of Ag髣 is nearly linear with two N atoms, and each L ligand links two Ag髣 atoms using its two imidazolyl N atoms to generate an infinite one-dimensional (1D) chain structure. The 1D chains are further connected by C-H.O hydrogen bonds to give a three-dimensional structure. CCDC: 609514.
The complex [Ag（L）]NO3 （1） [L=1,5-bis（imidazol-1-yl）pentane] was synthesized in ethanol and water, and characterized by elemental analysis and X-ray crystal structural analysis. The result shows that the complex crystallizes in monoclinic, space group P21/c with a=0.695 7（4） nm, b=0.988 7（4） nm, c=1.974 8（7） nm,β=91.934（19）°, V=1.357 5（10） nm^3, Z=4, Dcale=1.831 g·cm^-3, F（000）=752,μ=1.50 cm^-1, the final R=0.036 6, wR=0.091°. The coordination environment of Ag（I） is nearly linear with two N atoms, and each L ligand links two Ag（I） atoms using its two imidazolyl N atoms to generate an infinite one-dimensional （1D） chain structure. The 1D chains are further connected by C-H...O hydrogen bonds to give a three-dimensional structure. CCDC： 609514.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第8期1487-1490,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20231020)
关键词
晶体结构
银配合物
氢键
合成
crystal structure
Ag（I） complex
hydrogen bond
synthesis
