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机械振动对聚丙烯结晶作用的影响 被引量:1

THE EFFECT OF MECHANICAL VIBRATION ON CRYSTALLIZATION OF POLYPROPYLENE
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摘要 The testing specimens of an injected polypropylene sample were subjected to heat treatment for 30 min at various temperatures around its melting peak,and then the treated samples were characterized by DSC.It was found that there existed an temperature window at which the resulting melting temperature and crystallinity of the treated sample increased obviously.For heat treated specimens under static conditions the temperature window occured only below the peak melting temperature.For heat treated specimens under vibration in a dynamic mechanical analyzer with definite amplitude and frequency,this temperature window covered the whole melting range.Heat treating the PP sample under vibration in a temperature range of 5℃ above its melting peak,the resulting specimen possessed a maximum melting temperature. The testing specimens of an injected polypropylene sample were subjected to heat treatment for 30 min at various temperatures around its melting peak, and then the treated samples were characterized by DSC. It was found that there existed an temperature window at which the resulting melting temperature and crystallinity of the treated sample increased obviously. For heat treated specimens under static conditions the temperature window occured only below the peak melting temperature. For heat treated specimens under vibration in a dynamic mechanical analyzer with definite amplitude and frequency, this temperature window covered the whole melting range. Heat treating the PP sample under vibration in a temperature range of 5℃ above its melting peak, the resulting specimen possessed a maximum melting temperature.
出处 《高分子学报》 SCIE CAS CSCD 北大核心 2006年第4期620-623,共4页 Acta Polymerica Sinica
关键词 聚丙烯 振动作用 熔点 结晶度 Polypropylene, Vibration, Melt Temperature, Crystallinity
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