摘要
研究了兴安落叶松树皮栲胶废渣中木质素磺酸盐(LS)的混凝土应用性能、表面活性和分散性能。结果表明:树皮LS较木材LS具有更好的混凝土应用性能,且具有显著的表面活性,分散性能优越。其中,树皮LS对水泥的净浆流动度高于木材LS 98.1%,流动度损失在60 m in之后只有5.6%;起泡力比木材LS低46.4%;树皮LS 1%水溶液的表面张力为48.1 mN/m;树皮LS的CMC、σCMC分别为0.245%和54.5 mN/m。同时,比较了树皮LS与木材LS的结构特性。结果表明:树皮LS具有优良的应用性能是由于其具有较高的亲水基团含量,并且相对分子质量(Mr)分布比较均一。
The usages of bark lignosulfonate(LS) as concrete additive, surfactant and dispersant were studied. The results showed: bark LS had better performance than wood LS as additive in concrete, as surfactant and as dispersant, in which fluidity of cement paste using bark LS was 98.1% higher than that of wood LS, and drop of fluidity after 60 min was only 5.6 % ; foaming capacity was 46.4 % less than wood LS; surface tension at 1% was 48.1 mN/m; CMC and σCMC of bark LS were 0.245 % and 54.5 mN/m, respectively. Meanwhile, compared with wood LS on chemical structure characteristics, bark LS had higher content of hydrophilic groups and relatively narrower Mr distribution.
出处
《林产化学与工业》
EI
CAS
CSCD
2006年第3期59-62,共4页
Chemistry and Industry of Forest Products
关键词
树皮
木质素磺酸盐
栲胶废渣
bark residue
lignosulfonate
residue of tannin extracts