Synthesis of 3-Phenyl-6-formyl-3, 4-dihydro-2H-1, 3-benzoxazine 被引量：3

Synthesis of 3-Phenyl-6-formyl-3, 4-dihydro-2H-1, 3-benzoxazine

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摘要 A novel benzoxazine monomer containing aldehyde group, 3-phenyl-6-formyl-3, 4-dihydro-2H-1, 3-benzoxazine （Ald-B）, was synthesized via the Mannich condensation of formaldehyde, p-hydroxybenzaldehyde and aniline. Its structure was characterized by Fourier transform infrared spectroscopy （FTIR）, proton nuclear magnetic resonance （^1HNMR）. The side reaction in the synthesis is discussed. A novel benzoxazine monomer containing aldehyde group, 3-phenyl-6-formyl-3, 4-dihydro-2H-1, 3-benzoxazine （Ald-B）, was synthesized via the Mannich condensation of formaldehyde, p-hydroxybenzaldehyde and aniline. Its structure was characterized by Fourier transform infrared spectroscopy （FTIR）, proton nuclear magnetic resonance （^1HNMR）. The side reaction in the synthesis is discussed.

作者 Qi Chao RAN Qiao TIAN Yi GU

机构地区 State Key Laboratory of Polymeric Materials Engineering

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2006年第10期1305-1308,共4页 中国化学快报（英文版）

基金 We are grateful to the National Natural Science Foundation of China for financial support （No.90405001）.

关键词 BENZOXAZINE aldehyde group synthesis Schiff base. Benzoxazine, aldehyde group, synthesis, Schiff base.

分类号 O626.4 [理学—有机化学]

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1刘欣,顾宜.Effects of molecular structure parameters on ring-opening reaction of benzoxazines[J].Science China Chemistry,2001,44(5):552-560. 被引量：4
2石凤,段跃新,梁志勇,张佐光.RTM专用双马来酰亚胺树脂体系化学流变特性[J].复合材料学报,2006,23(1):56-62. 被引量：51
3姚福军,段跃新,肇研.RTM工艺树脂注射温度优化[J].复合材料学报,2007,24(3):105-108. 被引量：6
4吴晓青,李嘉禄.基于单向流动研究三维编织预制件的渗透性[J].复合材料学报,2007,24(3):116-120. 被引量：5
5Robertson F C. Resin transfer moulding of aerospace resins: A review[J]. British Polymer Journal, 1988, 20(5): 417-429.
6Shojaei A, Ghaffarian S R, Kari mian S M H. Modeling and si mulati on approac hes i n the resi n transfer mol di ng process: A revie w[J]. Pol ymer Composites, 2003, 24(4): 525-544.
7Ning X, Ishida H. Phenolic materials via ri ng - openi ng polymerization: Synthesis and characterization of bisphenol A based benzoxazines and their polymers[J]. Journal of Polymer Science Part A: Polymer Chemistry, 1994, 32(6): 1121-1129.
8Ran Qichao, Gu Yi. Investi gati on of processing, thermal, and mec hanical properties of a new composite matrix: Benzoxazine containing aldehyde group[J]. Polymers for Advanced Technologies, 2010, 21(3): 170-176.
9Xiang H, Ling H, Wang J, Song L, Gu Y. A novel high perf ormance RTM resin based on benzoxazine[J]. Polymer Composites, 2005, 26(5): 563-571.
10艾伦· 哈伯, 董雨达. 数脂传递模塑技术[M]. 哈尔滨: 哈尔滨工业大学出版社, 2002: 47.

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Chinese Chemical Letters

2006年第10期

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Synthesis of 3-Phenyl-6-formyl-3, 4-dihydro-2H-1, 3-benzoxazine 被引量：3

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