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EFFECTS OF DIFFERENT FUNCTIONAL GROUP-CONTAINING ORGANICS ON MORPHOLOGY-CONTROLLED SYNTHESIS OF SILVER NANOPARTICLES AT ROOM TEMPERATURE 被引量:5

EFFECTS OF DIFFERENT FUNCTIONAL GROUP-CONTAINING ORGANICS ON MORPHOLOGY-CONTROLLED SYNTHESIS OF SILVER NANOPARTICLES AT ROOM TEMPERATURE
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摘要 Silver nanoparticles with average particles sizes ranging from 2 to 131nm were manipulatively synthesized starting from silver nitrate using different functional group-containing organic modifiers at room temperature. The effects of the organic modifiers on the morphology of the resulting silver nanoparticles were strongly dependent on the intrinsic properties of the functional groups and the reducibility of the reductant. Numerous ether bonds (-0-)present in polyethylene glycol and Tween-80 were beneficial to the formation of silver nanoparticles with particle sizes of several nanometers in a narrow size distribution in both weak and strong reducing environments. Cetyltrimethylammonium bromide induced the formation of nanosized silver triangle plates in a weak reducing environment. The crystal growth of the silver nanoparticles with particle sizes of more than lOnm was postulated through an adhesion process of small-sized particles followed by a subsequent coalescence process under the present reaction conditions. Silver nanoparticles with average particles sizes ranging from 2 to 131nm were manipulatively synthesized starting from silver nitrate using different functional group-containing organic modifiers at room temperature. The effects of the organic modifiers on the morphology of the resulting silver nanoparticles were strongly dependent on the intrinsic properties of the functional groups and the reducibility of the reductant. Numerous ether bonds (-0-)present in polyethylene glycol and Tween-80 were beneficial to the formation of silver nanoparticles with particle sizes of several nanometers in a narrow size distribution in both weak and strong reducing environments. Cetyltrimethylammonium bromide induced the formation of nanosized silver triangle plates in a weak reducing environment. The crystal growth of the silver nanoparticles with particle sizes of more than lOnm was postulated through an adhesion process of small-sized particles followed by a subsequent coalescence process under the present reaction conditions.
出处 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2006年第5期362-370,共9页 金属学报(英文版)
关键词 silver nanoparticle NANOSTRUCTURE crystal growth TEM (transmissionelectron microscopy) silver nanoparticle nanostructure crystal growth TEM (transmissionelectron microscopy)
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