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铁精矿还原铁粉中酸不溶物的研究 被引量:8

ACID-INSOLUBLE SUBSTANCES IN REDUCED IRON POWDER FROM IRON CONCENTRATES
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摘要 X-光分析表明,铁精矿粉和用其还原的铁粉中的盐酸不溶物(AIC)为氧化物,其中约60%是六方和四方晶系的石英,其余40%为均含Si和Al的硅线石、氧化铝-氧化硅复合氧化物和一种未命名的沸石,它们无磁性,应易于从磁铁矿中选出。扫描电镜显示,其粒度为3~7μm,它们可能成为烧结体的裂纹源,从而损伤其力学性能。对精矿粉和矿石还原铁粉中的AIC进行了跟踪调查和统计分析,磁铁矿型精矿粉中AIC的平均值和标准差为(0.130±0.010)%,还原后AIC的预测值为(0.179±0.014)%,实测值为(0.192±0.014)%,两者仅差0.013%,这表明在还原和破碎过程中由于环境所造成的污染甚少。若严格控制选矿过程,将精矿粉AIC控制在0.07%左右,并防止还原时可能造成的污染,有可能得到AIC为0.12%-0.15%的优质矿石还原铁粉。 X-ray analysis results of iron ores and reduced iron powders revealed that around 60 % hydrochloric acid-insoluble substances were hexagonal and tetragonal quartz, another 40% substances were Si and AI containing, sillimanite,alumina-silicate, an unnamed zeolite, which are easily separated from magnetite powder. SEM images displayed that the particle size of acid-insoluble sustanees in the range of 3 - 7 μm, which may be the initial source of the cracks in the sintered body. Statistics analysis showed that the acid-insoluble content (AIC)of high-grade magnetite powder was (0.130± 0.010)%. The predicted AIC of reduced iron powder from ore powders should be(0. 179 ± 0.014) %. However,the measured value was(0. 192 ± 0.014) %. The difference of 0.013 % implies little pollution coming from the reduction and milling processes. A highgrade reduced iron powder eontainning 0.12- 0.15% AIC may be prepared if the AIC of ore powder is controlled to be less than 0.07 %.
出处 《粉末冶金工业》 CAS 北大核心 2006年第5期5-10,共6页 Powder Metallurgy Industry
关键词 铁粉 盐酸不溶物 铁精矿 Iron Powder AIC iron concentrates
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参考文献8

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