摘要
本文用热力学方法得到了一种能够预测Clausius-Clapeyron方程中积分常数的方法。本文也讨论了包括广泛使用的Antoine方程在内的其他蒸汽压方程中参数的预测以及关于饱和液体逸度的一种计算方法。不需要饱和蒸汽压或诸如正常沸点,临界压力等与饱和蒸气压直接有关的流体性质,用本文方法即可预测低。
A method to predict the integral constant in Clausius Clapeyron equation is obtained thermodynamically. The prediction of the constants in some other vapor pressure equations including widely used Antoine equation and a method to calculation the fugacity of saturated liquids are also discussed. No experimental vapor pressure data or directly related properties such as the boiling point and critical pressure are needed for the prediction.
出处
《上海第二工业大学学报》
1996年第2期23-29,共7页
Journal of Shanghai Polytechnic University
基金
上海自然科学基金