摘要
The azaanalog of copper phthalocyanine（azaCuPc） complex C 24H 8CuN 16 was prepared by the so- lid phase synthesis technology and its single crystals was characterized by high power Xray from the synchrotron radiation. The crystal belongs to monoclinic system, space group P21/n with a=1.612 3（3） nm, b= 0.529 40（11） nm, c=1.906 4（4） nm, β=105.25（3）°, V=1.569 9（5） nm, Z=2, Mr=584.00, Dc=1.235 g/cm3, F（000）=586, the final R=0.063 1 and wR=0.153 9 for 757 observed reflections with I>2σ（I）, GOF=1.340.
The azaanalog of copper phthalocyanine（aza-CuPc） complex C24H8 CuN16 was prepared by the solid phase synthesis technology and its single crystals was characterized by high power X-ray from the synchrotron radiation. The crystal belongs to monoclinic system, space group P21/n with a = 1. 612 3 （3） nm, b = 0.52940（11） nm, c=1.9064（4） nm, β=105.25（3）°, V=1.5699（5） nm, Z=2, Mr=584.00, Dc= 1. 235 g/cm^3, F（000） =586, the final R =0. 063 1 and wR =0. 153 9 for 757 observed reflections with I 〉 2σ（I）, GOF = 1. 340.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2006年第12期2263-2265,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金(批准号:60307002)资助.
关键词
固相法合成
氮杂酞菁铜
同步辐射
晶体结构
Solid phase synthesis
Azaanalog of copper phthalocyanine
Synchrotron radiation
Crystal structure
