期刊文献+

碳纳米管的氨基化对环氧树脂力学性能的影响 被引量:6

EFFECT OF CARBON NANOTUBES MODIFIED WITH TRIETHYLENETETRATMINE ON MECHANICAL PROPERTIES OF EPOXY RESIN COMPOSITE
下载PDF
导出
摘要 研究了三乙烯四胺(TETA)修饰的多壁碳纳米管(MWNT)对环氧树脂(EP)/MWNT复合材料力学性能的影响。结果显示,氨基化的短MWNT表面的TETA含量较高,修饰效果较好,在EP中分散性较好。添加1%左右的氨基化短MWNT复合材料的冲击强度、断裂伸长率、拉伸强度和弯曲强度较纯EP分别提高了163%、345%、80%和31%;氨基化的长MWNT比短MWNT复合材料的冲击强度和断裂伸长率分别高18.4%和10.2%;拉伸强度和弯曲强度则分别低4.2%和5.3%。 The influence of multiwall carbon nanotubes(MWNT) modified with triethylenetetramine on the mechanical properties of composites was investigated. Results showed that the content of TETA on the surface of short MWNT was high, and the modified short MWNT had good dispersibility in epoxy resin. Comparing with the pure epoxy resin, the impact strength, breaking elongation, the tensile strength and the bending strength of composites increased respectively 163%, 345%, 80% and 31% when the dosage of modified short MWNT in composites was 1.0%. Comparing with the long MWNT of 50 μm, the increase of tensile strength and bending strength achieved 4.2% and 5.3% respectively when the length of MWNT is 2 μm. But the impact strength and the breaking elongation decreased 18.4% and 10.2%.
出处 《工程塑料应用》 CAS CSCD 北大核心 2006年第12期8-12,共5页 Engineering Plastics Application
关键词 多壁碳纳米管 三乙烯四胺 环氧树脂 复合材料 力学性能 multiwall carbon nanotube, triethylenetetramine, epoxy resin, composite, mechanical properties
  • 相关文献

参考文献7

  • 1Andrews R, Weisenberger M C. Carbon nanotube polymer composites, Current Opinion in Solid State and Materials Science,2004,8(1):31
  • 2Dettlaff-Weglikowska U, Benoit J M, Chiu P W, et al. Chemical functionalization of single walled carbon nanotubes. Current Applyied Physics, 2002,2(6):497
  • 3Stevens J V,Huang A Y,Peng H Q,et al. Sidewall amino-functionalization of single-walled carbon nanotubes through fluorination and subsequent reactions with terminal diamines. Nano Letters, 2003,3 (3) :331
  • 4Saito T, Matsushige K, Tanaka K, et al. Chemical treatment and modification of muhi-walled carbon nanotubes. Physica B ,2002,323( 1 -4) : 280
  • 5曹春华,李家麟,贾志杰,陈正华.用二胺在碳纳米管上引入胺基团的研究[J].新型炭材料,2004,19(2):137-140. 被引量:26
  • 6肖素芳,王宗花,罗国安.碳纳米管的功能化研究进展[J].分析化学,2005,33(2):261-266. 被引量:30
  • 7Anglaret E, Dragin F, Penicaud A, et al. Raman studies of solutions of single-wall carbon nanotube salts. The Journal of Physical Chemistry B, 2006,110(9) :3949

二级参考文献59

  • 1[22]Wu B, Zhang J, Liu Z F, et al. Chemical alignment of oxidatively shortened single-walled carbon nanotubes on sliver surface[J]. J Phys Chem B, 2001, 105: 5075-5078.
  • 2[1]Iijima I. Helical microtubules of graphitic carbon[J]. Nature, 1991, 354: 56-58.
  • 3[12]Shi Z J, Lian Y F, Zhou X H, et al. Mass-production of single-wall carbon nanotubes by arc discharge method[J]. Carbon, 1999, 37(9): 1449-1453.
  • 4[13]Li F, Cheng H M, Xing Y T, et al. Purification of single-walled carbon nanotubes synthesized by the catalytic decomposition of hydrocarbons[J]. Carbon, 2000, 38: 2041-2045.
  • 5[15]Ebbesen T W, Ajayan P M, Hiura H, et al. Role of sp3 defect structures in graphite and carbon nanotubes[J]. Nature, 1994, 367: 148-149.
  • 6[16]Chen W, Li J L, Liu L, et al. Purification of carbon nanotubes using anodic oxidation in a solid polymer electrolyte(SPE) cell[J]. J App Electrochem, 2003, 33: 755-758.
  • 7[18]Liu J, Rinzler A G, Dai H J, et al. Fullerene pipes[J]. Science, 1998, 280: 1252-1256.
  • 8[19]Chen J, Hamon M A, Haddon R C, et al. Solution properties of single-walled carbon nanotubes[J]. Science, 1998, 282: 95-98.
  • 9[20]Sun Y, Wilson S R, Schuster D I. High dissolution and strong light emission of carbon nanotubes in aromatic amine solvents[J]. J Am Chem Soc, 2001, 123(22): 5348-5349.
  • 10[21]Liu Z F, Shen Z Y, Zhu T, et al. Organizing single-walled carbon nanotubes on gold using a wet chemical self-assembling technique[J]. Langmuir, 2000, 16(8): 3569-3573.

共引文献52

同被引文献181

引证文献6

二级引证文献36

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部