摘要
Eu（TTA）2（phen）（MA） complexes were synthesized, in which MA was introduced as the acidic ligand to increase the fluorescent intensity of the complexes. The complexes were characterized by scanning electron microscopy （SEM）, X-ray diffraction （XRD）, and fluorescent spectra, respectively. Different amounts of rare earth complexes were blended with silicon rubber over the melting point of Eu （TTA） 2 （phen） （MA）. Next, a definite amount of 2,5-dimethyl-2, 5-di （tert-butylperoxy） hexane was added as a cross linker to the composite, to get the uncured composites. Subsequently, the composites were vulcanized at 160℃, and silicon rubber-based composites with different contents of the complexes were prepared and their fluorescent properties were observed. The contents of rare earth complexes were 0.96 %, 2.83 %, 4.63 % and 6.36 % （mass fraction）, respectively. Moreover, the composites of Eu （TTA） 2 （phen） （ MA ）/SiR were measured by SEM, XRD, and fluorescent spectra. The measurement result shows that the fluorescent intensity of uncured rubber is similar to one of the pure rare earth complexes. However, there is no marked change of fluorescent intensity in the uncured rubber when the content of rare earth complexes continues to increase.
Eu（TTA）2（phen）（MA） complexes were synthesized, in which MA was introduced as the acidic ligand to increase the fluorescent intensity of the complexes. The complexes were characterized by scanning electron microscopy （SEM）, X-ray diffraction （XRD）, and fluorescent spectra, respectively. Different amounts of rare earth complexes were blended with silicon rubber over the melting point of Eu （TTA） 2 （phen） （MA）. Next, a definite amount of 2,5-dimethyl-2, 5-di （tert-butylperoxy） hexane was added as a cross linker to the composite, to get the uncured composites. Subsequently, the composites were vulcanized at 160℃, and silicon rubber-based composites with different contents of the complexes were prepared and their fluorescent properties were observed. The contents of rare earth complexes were 0.96 %, 2.83 %, 4.63 % and 6.36 % （mass fraction）, respectively. Moreover, the composites of Eu （TTA） 2 （phen） （ MA ）/SiR were measured by SEM, XRD, and fluorescent spectra. The measurement result shows that the fluorescent intensity of uncured rubber is similar to one of the pure rare earth complexes. However, there is no marked change of fluorescent intensity in the uncured rubber when the content of rare earth complexes continues to increase.
基金
Project supported by the National Natural Science Foundation of China and the China Energy Conservation InvestmentCorporation (50173004 and 50503002)
the Beijing New Star Project (2003A11) , the National High-Tech ResearchDeveloping Foundation (863 ,2003AA324030) and Beijing Municipal Commission of Education (JD100100403)
