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D-色氨酸印迹中空纤维复合膜制备及其性能 被引量:5

Properties of D-tryptophane molecular imprinting composite membranes and its preparation
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摘要 以聚砜(PSF)中空纤维超滤膜为基膜,采用表面紫外光聚合方法制备了D-色氨酸印迹中空纤维复合膜(CMIHFCM)。由SEM分析表明经过表面聚合后的D-色氨酸印迹中空纤维复合膜表面具有层叠交联状复合层,其厚度约3μm。实验结果表明D-色氨酸印迹中空纤维复合膜对模板分子D-色氨酸具有很好的识别作用,D,L-色氨酸的分离因子(α)最高可以达到5.0,大于非分子印迹复合膜的识别选择性。此外,引发剂的用量对D-色氨酸印迹中空纤维复合膜的识别性能有较大影响;当引发剂的浓度为1.0%,制得的D-色氨酸印迹中空纤维复合膜对D-色氨酸具有较好的识别性能,具有良好的应用前景。 Using polysulfone (PSF) hollow fiber membrane as the supporting membrane, chiral (D- tryptophane) molecular imprinted hollow fiber composite membrane (CMIHFCM) was fabricated by the surface photo-polymerization method and the recognition ability of CMIHFCM for D, L-tryptophane was studied. After surface polymerization, the external surface of CMIHFCM had a complex network layer with a thickness of 3 μm on the supporting membrane. The experimental results showed that CMIHFCM had the recognition ability for the template D-tryptophane. The D- tryptophane solution could be condensed more significantly by the molecular imprinted membrane than L-tryptophane, and the separation factor (α) of D-tryptophane (D-Trp) and L-tryptophane (L-Trp) could be 5.0. However, the recognition for D- tryptophane by the non-molecular imprinted membrane was weaker. When the concentration of initiator was 1.0%, CMIHFCM with good recognition abilitv for D-Trn was obtained.
出处 《化工学报》 EI CAS CSCD 北大核心 2007年第1期125-129,共5页 CIESC Journal
基金 国家重点基础研究发展计划项目(2003CB615705) 校基金项目 上海华谊(集团)公司-华东理工大学先进化学与化工技术研究中心基金项目~~
关键词 手性分子印迹 复合膜 手性识别 D-色氨酸 chiral molecular imprinting composite membrane chiral recognition D-tryptophane
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