摘要
Reiss and Pitzer’s theory on the melt of simple organic salt has been analysedand complemented. Based on the dynamic and thermodynamic melting model of ionicsalts, the factors which determine the melting points of simple ionic salts are proposed,they are the retiprocal of the sum of cationic radius and anionic radius ,the ratio of theradii of catation and anion and ionic non-spherical parameter. The melting points of alkalihalide melts, alkali-earth halide melts and alkali salts including non-spherical anion havebeen investigated by artificial neural network, with good result.
Reiss and Pitzer's theory on the melt of simple organic salt has been analysedand complemented. Based on the dynamic and thermodynamic melting model of ionicsalts, the factors which determine the melting points of simple ionic salts are proposed,they are the retiprocal of the sum of cationic radius and anionic radius ,the ratio of theradii of catation and anion and ionic non-spherical parameter. The melting points of alkalihalide melts, alkali-earth halide melts and alkali salts including non-spherical anion havebeen investigated by artificial neural network, with good result.
出处
《物理化学学报》
SCIE
CAS
CSCD
北大核心
1996年第12期1103-1105,共3页
Acta Physico-Chimica Sinica
基金
国家自然科学基金
关键词
无机盐
熔点
神经网络法
Inorganic salt, Melting point, Artificial neural network method
