摘要
对羧基偶氮氯膦及其与钇络合物的光化学、电化学性能研究卢燕曲连家杨茹CPApK是七元酸,随溶液碱性的增加,试剂逐级离解,第1~5级离解分别为两个SO3H及一个PO3H2、一个COOH中H+的离解,第六、七级离解为萘环上两个羟基中H+的离解,本实验测定n...
Optics and electrochemistry properties of CPApK and the complex with yttrium (Y) were discussed.The protonation constant (2 233),the protonation number (1), the dissociation constant(9 877) were determined.CPApK and the complex with Y (CPApK∶Y=2∶1)have absorptive property on mercury electrode.The reaction of reduction between them is unreversible reaction and produce polarographic adsorptive wave.
出处
《山东建材学院学报》
1996年第3期43-47,共5页
Journal of Shandong Institute of Building Materials
关键词
对羧基偶氮氯膦
钇
光化学性能
电化学性能
p carboxychlorophosphonazo
yttrium
optics and electrochemistry properties