期刊文献+

PEG-ZnO-PP复合抗静电剂及其对聚丙烯纤维的改性 被引量:5

PEG-ZnO-PP composite antistatic agent and its modification for polypropylene fiber
下载PDF
导出
摘要 选用相对分子质量分别为10 000和20 000的聚乙二醇(PEG 10000,PEG 20000)与氧化锌(ZnO)、马来酸酐(MAH)混合,再与聚丙烯(PP)共混,制备复合抗静电剂(PEG-ZnO-PP),然后将其与PP共混纺丝,制得共混纤维。研究了PEG-ZnO-PP复合抗静电剂的流动性和热性能,考察了共混纤维的力学性能和抗静电性。结果表明:复合抗静电剂的流动性和热性能因PEG的相对分子质量不同而有所不同,含PEG 10000的复合抗静电剂的流动性能较好,且其熔融热焓、熔融结晶温度、结晶放热高于含PEG 20000的复合抗静电剂。共混纤维力学性能和静电半衰期随复合抗静电剂含量的增加而减小,含PEG 20000的共混纤维抗静电效果更好。 PEG-ZnO-PP composite antistatic agent can be prepared by mixing polyethylene glycol with relative molecular weight of 10 000 and 20 000 (PEG 10000, PEG 20000) with zinc oxide (ZnO)and maleic anhydride(MAH) and blending with polypropylene ( PP), which was blend spun with PP to produce blend fiber. The fluidity and thermal property of PEG-ZnO-PP com- posite antistatic agent were studied. The mechanical properties and antistatic behavior of the blend fiber were investigated. The results showed that the fluidity and thermal property of the composite antistatic agent varied with the relative molecular weight of PEG. The composite antistatic agent containing PEG 10000 was better in fluidity and had higher enthalpy of melting, melting crystallization temperature and crystallization exothermicity than that containing PEG 20000. The mechanical properties and static half-life of blend fiber were decreased with the addition of the composite antistatic agent. The composite antistatic agent containing PEG 20000 was better in antistatic behavior.
出处 《合成纤维工业》 CAS CSCD 北大核心 2007年第1期31-33,共3页 China Synthetic Fiber Industry
关键词 聚丙烯纤维 复合抗静电剂 性能 聚乙二醇 氧化锌 共混 polypropylene fiber composite antistatic agent property polyethylene glycol zinc oxide blending
  • 相关文献

参考文献5

二级参考文献13

  • 1阮德水,张太平,张道圣,梁树勇,胡起柱.相变贮热材料的DSC研究[J].太阳能学报,1994,15(1):19-24. 被引量:52
  • 2董擎之.聚丙烯切片流变性能的研究[J].金山油化纤,1995,14(1):1-4. 被引量:3
  • 3贾志杰.碳纳米管/高分子复合材料的研究:博士学位论文[M].北京:清华大学,1999..
  • 4高绪珊 童Yan.-[J].纺织学报,1991,12(12):540-540.
  • 5Xu Ruiyun , et al . Studies of solid-solid phase transitions for (n-C18H37NH3)2MCl4[J]. Thermochimca , 1990 , (164) : 307~314 .
  • 6张寅平 胡汉平 孔祥东.相变储能-理论与应用[M].合肥:中国科学技术大学出版社,1996.2-31.
  • 7Gong Z X , Mujumdar A R . Cyclic heat transfer in a novel storage unit of multiple phase change materials[J]. Appl. Therm. Eng. , 1996 , 16 (10) : 807~815.
  • 8Syed M T , Kumar S , Moallemi M K , et al . Thermal storage using form-stable phase-change materials[J]. Ashrae Journal , 1997 , 39 (5) : 46~50.
  • 9Jinan C, Kikutant T, Takaku A. Nonisothernal Orientation-induced Crystallization in Melt Spinning of Polypropylene [ J ].J Appl Polym Sci, 1989, (37) :2 633 -2 697
  • 10常玉红,许际清.通用塑料抗静电剂的现状与开发[J].陕西化工,1998,27(2):10-11. 被引量:9

共引文献45

同被引文献68

引证文献5

二级引证文献24

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部