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铈锆摩尔比对Ce_(0.3+x)Zr_(0.6-x)Y_(0.1)O_(1.95)系列储氧材料性能的影响 被引量:7

Effect of Cerium/Zirconium Molar Ratio on the Property of Series OSM Ce_(0.3+x)Zr_(0.6-x)Y_(0.1)O_(1.95)
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摘要 A series of materials Ce0.3+xZr0.6-xY0.1O1.95 were prepared by co-precipitation routine and the property of these materials was studied by means of oxygen storage capacity, temperature programming reduction, X-ray diffraction, transmission electronic microscope, and X-ray photoelectron spectroscopy. The results indicate that the materials with a low Ce/Zr molar ratio possess higher cerium atom utilization ratio, reducibility and thermal stability than the materials with a high Ce/Zr ratio, and Ce0.35Zr0.55Y0.1O1.95 possesses the best properties. A series of materials Ce0. 3 +xZr0. 6-xY0.1O1. 95 were prepared by co-precipitation routine and the property of these materials was studied by means of oxygen storage capacity, temperature programming reduction, X-ray diffraction, transmission electronic microscope, and X-ray photoelectron spectroscopy. The results indicate that the materials with a low Ce/Zr molar ratio possess higher cerium atom utilization ratio, reducibility and thermal stability than the materials with a high Ce/Zr ratio, and Ce0.35Zr0.55Y0.1O1.95 possesses the best properties.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2007年第3期559-561,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金(批准号:20273043) 国家自然科学重点基金(批准号:20333030)资助
关键词 储氧材料(OSM) 储氧量(OSC) 铈锆比[n(Ce)/n(Zr)] 铈原子利用率 Oxygen storage material(OSM) Oxygen storage capacity (OSC) Cerium/zirconium molar ratio[ n(Ce)/n(Zr) ] Cerium atom utilization ratio
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