摘要
合成了一种新型杂多酸荷移盐(C5H10NH2)4PMo11VO40,并用元素分析、红外光谱对其进行表征.对配合物的结构分析表明:化合物中的多阴离子仍保留着其Keggin结构,但其特征振动谱带有一定的蓝移.结果表明形成电荷转移盐之后的杂多阴离子PMo11VO404-通过静电引力与C3N5H4NH3+作用.
A novel charge transfer salt （C5H10NH2）4PMo11VO40 has been synthesized and characterized by means of elemental analysis and [R spectrum. For （C5H10NH2）4PMo11VO40 ,structural analysis suggested that heteropoly anion in this compound was reserved its Keggin structure, but the characteristic vibrational bands have some blue shifts. The results show that the stronger interactions and charge transfer existing PMo11VO40^4- and C3N5H4NH3^＋.
出处
《吉林化工学院学报》
CAS
2007年第1期1-2,9,共3页
Journal of Jilin Institute of Chemical Technology
基金
国家自然科学基金资助项目(20371012)
