期刊文献+

淀粉醋酯化催化剂的探索

Study on the esterification catalysts of starch acetates
下载PDF
导出
摘要 以木薯淀粉为原料,用醋酸酐为酯化剂,以乙酸为分散递质,探索了以浓硫酸、对甲基苯磺酸、十二烷基苯磺酸为催化剂对淀粉醋酯化反应的影响.用红外光谱对反应产物的结构进行鉴定.实验结果表明:十二烷基苯磺酸可以作为淀粉酯化的催化剂. The effect of the catalysts, e.g., concd, sulfuric acid, p-toluenesulfonic acid, dodecylbenzenesulfonic acid on the esterification of starch was studied with cassava starch as the raw material, acetic anhydride as the esterifying agent and acetic acid as the dispersion medium. The product structures were detd. by IR spectra. The exptl, results demonstrated that dodecylbenzenesulfonic acid could be used as the catalyst for starch esterification.
出处 《印染助剂》 CAS 2007年第4期14-16,共3页 Textile Auxiliaries
关键词 木薯淀粉 醋酯化淀粉 酯化 催化剂 取代度 cassava starch acetated starch esterification catalysts substitution degree
  • 相关文献

参考文献5

  • 1董琪,朱颖先,陈大俊.高直链淀粉醋酸酯的合成与表征[J].化学世界,2003,44(8):408-411. 被引量:5
  • 2惠斯特勒 R L,贝密勒 J N,帕斯卡尔 E F.淀粉的化学与工艺学[M].王雒文,闵大铨,译.北京:中国食品出版社,1988.
  • 3Glenn M M,Calvin G T.Process for acetylation of cellulose[P].世界专利:WO 9403497,1994—02—17.
  • 4Wininger,Brice S.Method of Preparing Cellulose Esters[P].美国专利:US4329446.1982-05-11.
  • 5Royal,Whistleh.Starch:chemistry and technology[M].Harcourt Brace Jovanich:AP Press Inc,1984.26-27.

二级参考文献7

  • 1Maheras J C, Hopkins Jr, et al. Polymer blend comosed of cellulose acetate and starch acetate used to form fibers, films and plastic materials and process to prepare said blend[P]. US:5 507 304,1996.
  • 2Brochers G D, et al. Esterified starch composition[P]. US:5 587 412,1996.
  • 3Tanaka H U, et al. Method for producing starch esters, starch esters, and starch ester compositions[P].US:5 714 600,1998.
  • 4Cheetham W H N, Tao Liping. Variation in crystalline type with amylose content in maize starch granules: an X-ray powder diffraction study[J]. Carbohydrate Polymers, 1998,36 : 277.
  • 5Miladinov V D, Hanna M A. Physical and molecular properties of starch acetates extruded with water and ethanol [J]. Industrial Engineering of Chemical Research, 1999,38 : 3892.
  • 6Soest J J G van, Hulleman S H D. Changes in the mechanical properties of thermoplastic potato starch in relation with changes in B-type crystallinity[J]. Carbohydrate Polymers, 1996,29:225.
  • 7朱颖先,王月,李瑶君,陈大俊.高取代度淀粉醋酸酯的制备[J].应用化学,2001,18(7):592-594. 被引量:16

共引文献11

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部