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纳米TiO_2/再生纤维素复合薄膜的制备及光催化性能 被引量:23

Preparation and photocatalytic activity of nano-TiO_2/regenerated cellulose composite films
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摘要 在1烯丙基3甲基咪唑氯室温离子液体中,将纳米TiO2粉末与纤维素浆粕进行溶液共混,所得纤维素用水再生后,经过超临界CO2干燥处理,制备了不同TiO2含量的纳米TiO2/再生纤维素复合膜。通过扫描电子显微镜(SEM)、X射线衍射(XRD)、傅立叶变换红外光谱(FTIR)对所得薄膜的形貌、结构进行表征。利用PCC-2型光催化活性检测仪测试薄膜在紫外光下光催化降解亚甲基蓝的能力,评价薄膜的光催化活性。讨论了纳米TiO2含量、超临界CO2干燥和真空干燥对薄膜性能的影响。结果表明:复合膜的光催化活性达到所用TiO2粉体的90%;经超临界CO2干燥处理所得复合膜的光催化活性明显高于真空干燥所得复合膜的活性;纳米复合膜的光催化活性随TiO2含量的增加先升高后降低,含量为5%时光催化活性最高。 Nano-TiO2/regenerated cellulose films with different titania contents were prepared by directly blending titania powder and cellulose (pulp) in 1-allyl-3-methylimidazolium chloride ionic liquid at room temperature. The cellulose was regenerated by water and then dried by supercritical CO2. The morphology, phase components, structure and thermal property of the films were characterized by SEM, XRD and FTIR. The photocatalytic activities of the films were evaluated for decomposition of the methylene blue under UV light irradiation by PCC-2 photocatalysis evaluation checker. The influencing factors on photocatalytic activity of the films were discussed, such as the content of nano-TiO2 and the drying methods of supercritical CO2. The results show that, with the addition of titania, the photocatalytic activity of the films treated by supercritical CO2 medium is higher than that of films dried in vacuum. The photocatalytic activity of the films increases with the increasing of nano-TiO2 particles up to 5 % and then decreases with the increasing of TiO2 content.
出处 《复合材料学报》 EI CAS CSCD 北大核心 2007年第3期35-39,共5页 Acta Materiae Compositae Sinica
基金 国家重点基础研究发展计划(2004CB719701)
关键词 纳米TIO2 再生纤维素 复合膜 室温离子液体 光催化活性 nano-TiO2 regenerated cellulose composite film room temperature ionic liquid photocatalytic activity
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  • 1Phillips D M,Drummy L F,Conrady D G,et al.Dissolution and regeneration of bombyx mori silk fibroin using ionic liquids[J].J Am Chem Soc,2004,126(44):14350-14351.
  • 2Welton T.Room-temperature ionic liquids solvents for synthesis and catalysis[J].Chem Rev,1999,99(8):2071-2084.
  • 3Swatloski R P,Spear S K,Holbrey J D,et al.Dissolution of cellose with ionic liquids[J].J Am Chem Soc,2002,124(18):4974-4975.
  • 4刘瑞刚,胡学超,章潭莉.棉纤维素在NMMO中溶解前后结晶结构的变化[J].中国纺织大学学报,1998,24(4):7-10. 被引量:107
  • 5Kendall J L,Canelas D A,Young J L,et al.Polymerizations in supercritical carbon dioxide[J].Chem Rev,1999,99(2):543-564.
  • 6王进,程兴国,袁明君,何嘉松.超临界CO_2在微孔聚合物制备中的应用[J].高分子通报,2001(6):8-17. 被引量:25
  • 7Jin H,Nishiyama Y,Wada M.Nanofibrillar cellulose aerogels[J].Colloids and Surfaces A:Physicochem Eng Aspects,2004,240:63-67.
  • 8Meilert K T,Laub D,Kiwi J.Photocatalytic self-cleaning of modified cotton textiles by TiO2 clusters attached by chemical spacers[J].J Mol Catal A:Chem,2005,237:101-108.
  • 9Kemell M,Pore V,Ritala M,et al.Atomic layer deposition in nanometer level replication of cellulosic substances and preparation of photocatalytic TiO2/cellulose composites[J].J Am Chem Soc,2005,127(41):14178-14179.
  • 10Zhang Hao,Wu Jin,Zhang Jun,et al.1-Allyl-3-methylimidazolium chloride room temperature ionic liquid:A new and powerful nonderivatizing solvent for cellulose[J].Macromolecules,2005,38(20):8272-8277.

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