摘要
采用溶胶-凝胶法合成MoO3/TiO2、K2O-MoO3/TiO2、V2O5-MoO3/TiO2、Al2O3-MoO3/TiO2、K2O-V2O5-MoO3/TiO2系列纳米催化剂。借助TEM、XRD、IR等技术对催化剂进行了表征,并利用环己烷催化氧化脱氢成环己烯的反应进行活性测试。结果表明,MoO3在载体TiO2呈单层和多层分布,单层分布时发生了Mo与O—Ti的键合作用,同时使TiO2表面水分子发生解离反应,活化时脱去—OH产生Mo6+和Mo—O-活性中心;多层分布时以MoO、Mo—O-活性物种为主。脱氢中心和供氧中心之间存在协同作用,K、Al、V均能影响其协同作用。
Abstract： A series of MoO3/TiO2, K2O-MoO3/TiO2, V2O3-MoO3/TiO2, Al2O3-MoO3/TiO2 and K2O- V2O3-MoO3/TiO2 were prepared by the sol-gel method, and characterized with TEM, XRD and IR. The catalytic activity of oxydehydrogenation of cyclohexane to cyclohexene was tested. The results showed that MoO3 was distributed on the carrier of TiO2 with monolayer or/and muhilayer. The Mo in the monolayer was bonded with O-Ti structure, and caused dissociation of the water molecules on the surface of TiO2, and the activity centre of Mo^6＋ and Mo-O^- species were formed by means of activation to eliminate the hydroxyl group. For the muhilayer structure the main active species were Mo=O and Mo-O^- . A synergetic effect existed between the dehydrogenation centre and the oxygen-supply centre, and was affected by the addition of K, Al or V.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2007年第6期1451-1456,共6页
CIESC Journal
基金
湖南省自然科学基金项目(06JJ4009)。~~
关键词
纳米催化剂
合成
环己烷
环己烯
活性物种
nanocatalyst
synthesis
cyclohexane
cyclohexene
active species
