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菌丝体表面分子印迹吸附剂的选择性吸附 被引量:8

Selective adsorption of surface molecular imprinted adsorbent based on mycelium
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摘要 采用制备得到的菌丝体表面分子印迹吸附剂,系统研究了菌丝体表面分子印迹吸附剂对模板金属离子的吸附选择性。结果表明:与非印迹吸附剂相比,以Ni2+为模板制备的菌丝体表面分子印迹吸附剂,对Ni2+、Cu2+与Cr3+的吸附速率和吸附容量都有较大幅度的提高。对于含有Ni2+的金属离子混合溶液,菌丝体表面分子印迹吸附剂对Ni2+的吸附容量和选择性都比另一种金属离子(如Cr3+和Cu2+)明显提高;与非印迹吸附剂相比,印迹吸附剂对非模板金属离子Cr3+和Cu2+的选择性明显降低。 Using a new chitosan molecular imprinted adsorbent based on the mycelium of waste biomass (surface imprinted adsorbent), the adsorption selectivity of the surface imprinted adsorbent for the template ion was studied. The results showed that, compared with the surface non-imprinted adsorbent, the adsorption capacity and rate for three ions (Ni^2+ , Cr^3+ , Cu^2+) of the surface imprinted adsorbent with Ni^2+ as template ion increased considerably. In the presence of the template ion (Ni^2+ ) and other ions in solution, the adsorption capacity and selectivity for the template ion (Ni^2+) of the surface imprinted adsorbent were higher than those of another ion (such as Cr^3+ or Cu^2+). However compared with the surface non-imprinted adsorbent, the adsorption selectivity for the non-template ions (Cr^3+ and Cu^2+) obviously decreased.
出处 《化工学报》 EI CAS CSCD 北大核心 2007年第6期1473-1477,共5页 CIESC Journal
基金 国家自然科学基金项目(20136020 20406002)。~~
关键词 菌丝体表面分子印迹吸附剂 选择性吸附 金属离子 分子印迹 生物吸附 surface imprinted adsorbent selective adsorption metal ion molecular imprinting biosorption
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参考文献14

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二级参考文献3

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