摘要
The pyrolysis characteristics of PVC were systematically investigated using a Netzschne TG thermo-balance coupled to a quadrupole mass spectrometer. The pyrolysis conditions were 0.1 MPa of Ar, a heating rate of 10 ℃/min and a final temperature of 1000℃. Both the thermogravimetric properties and the simultaneous evolution of gaseous products during pyrolysis were studied. The TG/DTG results showed that as the pyrolysis temperature increases the weight loss and weight loss rate of PVC increases. Near 412℃ the weight loss rate attained its peak value. At higher temperatures the rate of loss gradually decreases. The gases evolved during thermogravimetric analysis were analyzed by a mass spectrometer, monitoring the relative intensity of HC1, C6H6, light hydrocarbon and chlorine-containing gases The evolution curves showed that HC1, C6H6, light hydrocarbon and chlorine-containing gases all peak at about 416℃. This is consistent with the fact that the weight loss curves also peak at about 412℃. The extensive HCl evolution is consistent with the high chlorine content of PVC. The formation of these gases can be explained by considering these reactions： dehydrochlorination, intramolecular cyclization and the addition of HCl to unsaturated hydrocarbons.
The pyrolysis characteristics of PVC were systematically investigated using a Netzschne TG thermo-balance coupled to a quadrupole mass spectrometer. The pyrolysis conditions were 0.1 MPa of Ar,a heating rate of 10 ℃/min and a final temperature of 1000 ℃. Both the thermogravimetric properties and the simultaneous evolution of gaseous products during pyrolysis were studied. The TG/DTG results showed that as the pyrolysis temperature increases the weight loss and weight loss rate of PVC increases. Near 412 ℃ the weight loss rate attained its peak value. At higher temperatures the rate of loss gradually decreases. The gases evolved during thermogravimetric analysis were analyzed by a mass spectrometer,monitoring the relative intensity of HCl,C6H6,light hydrocarbon and chlorine-containing gases. The evolution curves showed that HCl,C6H6,light hydrocarbon and chlorine-containing gases all peak at about 416 ℃. This is consistent with the fact that the weight loss curves also peak at about 412 ℃. The extensive HCl evolution is consistent with the high chlorine content of PVC. The formation of these gases can be explained by considering these reactions: dehydrochlorination,intramolecular cyclization and the addition of HCl to unsaturated hydrocarbons.
基金
Project 2005BS09003 supported by Shandong Province Foundation for Distinguished Young Scholars
