期刊文献+

氧化钴多孔薄膜的电化学制备及其超电容性能 被引量:2

Study on Preparation and Capacitive Properties of CoO_x.yH_2O Porous Films Fabricated by Electrochemical Method
下载PDF
导出
摘要 采用恒电流沉积方法,以0.2 mol/L CoSO4+1.5 mol/L H2SO4为电镀液,在阴极大电流密度下,以氢气泡为模板,在石墨基体上成功制备了CoOx.yH2O多孔薄膜.通过扫描电子显微镜、循环伏安法和恒电流充放电技术等对CoOx.yH2O多孔薄膜的形貌及超电容性能进行表征和研究,并对CoOx.yH2O多孔薄膜的沉积机理进行了探讨.结果表明:CoOx.yH2O薄膜呈纳米/亚微米级的多孔结构,随阴极电流密度的增加,薄膜的孔径增大;同时,膜层具有优异的充放电性能和功率特性,比电容达64.8 F·g-1,并具有良好的稳定性. CoOx·yH2O porous films were electrodeposited successfully on graphite electrode with a high cathodic current density in 0.2 mol/L COSO4 + 1.5 mol/L H2SO4 aqueous solution through H2 gas template. The micrographs of the CoOx·yH2O porous films were characterized by scanning electron microscopy (SEM), and the capacitive properties of the CoO·yH2O porous film/graphite electrode were investigated in 2 M KOH by cyclic voltammetry and galvanostatic charge-discharge method. The CoOx·yH2O porous film/graphite electrode exhibited a high electrochemical reversibility, high power characteristics and excellent charge-discharge proper- ty, A specific capacitance of 64.8 F·g^-1 was obtained at a charge-discharge current density of 0.2 mA·cm^-2 Only 9.1% loss of the specific capacitance was found after 1 400 charge-discharge cycles, which demonstrates that the CoOx·yH2O porous film/graphite electrode has excellent long-term cycle stability.
出处 《湖南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2007年第6期44-48,共5页 Journal of Hunan University:Natural Sciences
基金 湖南省自然科学基金资助项目(04JJ1008) 高等学校博士学科点专项科研基金资助项目(20040532006)
关键词 氧化钴 电沉积 多孔 超电容 cobalt oxides electrodeposition porous supercapacitor
  • 相关文献

参考文献8

  • 1ZHENG J P, JOW T R. A new charge storage mechanism for electrochemical capacitor[J]. J Electrochem Soc, 1995, 142( 1 ) : L6 -L8.
  • 2LIU X M, ZHANG Y H. Studies on Me/Al-layered double hydroxides(Me= Ni an Co)as electrode materials for electrochemical capacitors[J]. Electrochim Acta,2004,49: 3137- 3141.
  • 3ADRIANA R,DE S, EVERALDO A. Paeudocapacitive behavior of Ti/RhOx + Co3O4 dectrodes in acidic medium: application to supercapacitor development[J]. Electrochim Acta,2004,49:2015 - 2023.
  • 4CHUANG P Y, HU C C. The electrochemical characteristics of binary manganese-cobalt oxides prepared by anodic deposition[J]. Mater Chem Phys, 2005,92 : 138 - 145.
  • 5CHUAN L,JAMES A,BRANKO N P. Characterization of solgel derived cobalt xergels as eletrochemical capacitor [J ]. J Electrochem Soc, 1998, 145:4097 - 4100.
  • 6原长洲,张校刚,高博.多孔Co(OH)_2的制备及其超电容特性[J].应用化学,2006,23(4):456-458. 被引量:23
  • 7SHINDE V R, MAHADIK S B. Supercapacitive cobalt oxide (Co3O4) thin films by spray pyrolysis[J]. Appl Surf Sci,2006, 252(20 ) : 7487 - 7492.
  • 8SUGIMOTO W,KIZAKI T. Evaluation of the pseudocapacitance in RuO2 with a RuO2/GC thin film electrode[J]. Electrochim Acta, 2004,49 : 313 - 320.

二级参考文献8

  • 1Bonnefoi L,Simon P,Fauvarque J F,et al.J Power Sources[J].1999,83:162
  • 2Liang Y-Y,Cao L,Li H-L,et al.J Power Sources[J].2004,136:197
  • 3Conway B E.J Electrochem Soc[J].1991,138(6):1
  • 4XingW,Li F,YanZ-F,et al.J Power Sources[J].2004,134:324
  • 5Sumit B,Ashwin S P,Madhusudhan R,et al.Langmuir[J].2003,19:5 522
  • 6Larsen G,Lotero E,Nabity M,et al.J Catal[J].1996,164:246
  • 7Liu X-M,Zhang X-G,Fu S-Y,et al.Electrochim Acta[J].2004,49:3 137
  • 8张密林,刘志祥.沉淀转化法制备的Co(OH)_2的超级电容特性[J].无机化学学报,2002,18(5):513-517. 被引量:26

共引文献22

同被引文献15

引证文献2

二级引证文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部