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Co_3O_4的制备及电容性能的研究 被引量:8

Preparation and study on the capacitance performance of Co_3O_4
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摘要 用KOH作沉淀剂制备Co(OH)2前驱体,并用热分解法制备了Co3O4粉末,XRD表明所制备的Co3O4是立方相。采用循环伏安、恒流充放电等研究了样品的电化学性能。结果表明:Co3O4电极在5 mol/L KOH溶液中,0-0.4 V的电位范围内,电流密度为5 mA/cm^2时,放电比电容可达300.59 F/g。 Co(OH)2 precursor was prepared by KOH as precipitating agent and then Co304 powder was synthesized by the thermolysis method, XRD indicated that the crystalline type of Co304 was cube. Electrochemical performance of the sample was studied by cyclic vohammetry and galvanostaitc charge-dlscharge. The results showed that the specific discharge capacitance of Co3O4 electrode was 300.59 F/g in the 5 mol/L KOH solution within 0 - 0.4 V potential and at 5 mA/cm^2 current density.
出处 《电池》 CAS CSCD 北大核心 2007年第2期141-142,共2页 Battery Bimonthly
基金 教育部博士点基金(20050217019)
关键词 超级电容器 CO3O4 沉淀法 电容性能 supercapacitor Co3O4 precipitation method capacitance performance
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参考文献6

  • 1杨惠,石兆辉,陈野,张密林.金属氧化物超级电容器的研究进展[J].电池,2005,35(6):477-479. 被引量:7
  • 2程杰,李晓忠,曹高萍,沈涛,杨裕生.活性炭-烧结复合镍钴超级电容器[J].电池,2005,35(3):166-168. 被引量:13
  • 3Nam K W,Yoon W S,Kim K B.X-ray absorption spectroscopy studies of nickel oxide thin film electrodes for supercapacitors[J].Electrochimica Acta,2002,47(19):3 201-3 209.
  • 4Tototzintle-Huitle H,Prokhorov E,Mendoza-Galván A,et al.Study of the formation of Co3O4 thin films using sol-gel method[J].J Physics and Chemistry of Solids,2003,64(6):975-980.
  • 5García-Pacheco G,Cabanas-Moreno J G,Yee-Madeira H,et al.Co3O4 nanoparticles produced by mechanochemical reactions[J].Nanotechnology,2006,17(10):2 528-2 535.
  • 6Svegl F,Orel B,Hutchine M G,et al.Structural and spectroelectrochemical investigations of sol-gel derived electrochromic spinel Co3O4 films[J].J Electrochem Soc,1996,143 (5):1 532-1 539.

二级参考文献26

  • 1张治安,邓梅根,汪斌华,胡永达,杨邦朝.电化学混合电容器[J].电池,2004,34(4):295-297. 被引量:19
  • 2Conway B E. Electrochemical Supercapacitors: Scientific Principles and Technological Applications[M]. New York: Plenum, 1999.
  • 3Pell W G, Conway B E, William A, et al. Electrochemical efficiency in multiple discharger/recharge cycling of supercapacitors in hybrid EV applications[J]. J Power Sources, 1999, 80(1-2): 134-141.
  • 4XIEJing-ying(谢晶莹) WANGXiao-feng(王晓峰) ZHANGQuansheng(张全生) etal.电化学超级电容器及其制造方法[P].CN:1277444.2000-12-20.
  • 5CHENGJie(程杰) CAOGao-ping(曹高萍) YANGYu-sheng(杨裕生).烧结镍电极的电化学电容性能初探[A]..中国电化学会12届年会论文集[C]:中国电化学会12届年会[C].Shanghai(上海),2003..
  • 6Kotz R, Carlen M. Principles and applications of electrochemical capacitors[J]. Elcctrochimica Acta, 2000, 45(15 - 16):2 483 -2 498.
  • 7ZHUSong-ran(朱松然).蓄电池手册[M].Tianjin(天津):Tianjin University Press(天津大学出,1998..
  • 8Osaka T, Liu X, Nojima M. Acetylene black/poly (vinylidene fluoride) gel electrolyte composite electrode for an electric doublelayer capacitor[J]. J Power Sources, 1998, 74(1): 122- 128.
  • 9CAOChu-nan(曹楚南) ZHANGJian-qing(张鉴清).电化学阻抗谱导论[M].Beijing(北京):Beijing Science Press(北京科学出版社,2002..
  • 10Burk A F.Ultracapacitors:why,how,and where is the technology[J].J Power Sources,2000,91(1):37-50.

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