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Synthesis, Crystal Structure and Characterization of a One-dimensional Supramolecular Rare Earth Complex of N-(6-(4-Methylpyridinyl))ketoacetamide

Synthesis, Crystal Structure and Characterization of a One-dimensional Supramolecular Rare Earth Complex of N-(6-(4-Methylpyridinyl))ketoacetamide
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摘要 A one-dimensional (1D) supramolecular rare earth complex [Nd(NO3)2L2-(C3H6O)][NdL(NO3)4]} (L=N-(6-(4-methylpyridinyl))ketoacetamide) has been prepared and characterized by elemental analysis, IR and electronic spectroscopy, and single-crystal X-ray diffraction. The crystal crystallizes in the triclinic system, space group P1^- with a=0.9146(6), b=1.2581(8), c=2.2316(14) nm, α=99.352(10),β=97.209(9), γ=103.935(9)°, V=2.422(3) nm3, Dc=1.776 g/cm^3, C33H42N12Nd2O25, Mr=1295.27, Z=2, F(000)=1288, μ=2.217 mm-1, R=0.0508and wR=0.1046 for 5173 observed reflections (I 〉 2σ(I)). In the structure of the title complex,one-dimensional supramolecular double-chains are formed by intermolecular hydrogen bonding interactions. A one-dimensional (1D) supramolecular rare earth complex [Nd(NO3)2L2-(C3H6O)][NdL(NO3)4]} (L=N-(6-(4-methylpyridinyl))ketoacetamide) has been prepared and characterized by elemental analysis, IR and electronic spectroscopy, and single-crystal X-ray diffraction. The crystal crystallizes in the triclinic system, space group P1^- with a=0.9146(6), b=1.2581(8), c=2.2316(14) nm, α=99.352(10),β=97.209(9), γ=103.935(9)°, V=2.422(3) nm3, Dc=1.776 g/cm^3, C33H42N12Nd2O25, Mr=1295.27, Z=2, F(000)=1288, μ=2.217 mm-1, R=0.0508and wR=0.1046 for 5173 observed reflections (I 〉 2σ(I)). In the structure of the title complex,one-dimensional supramolecular double-chains are formed by intermolecular hydrogen bonding interactions.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2007年第8期877-882,共6页 结构化学(英文)
基金 This work was supported by the National Natural Science Foundation of China (No. 20401008)
关键词 crystal structure rare earth nitrate Β-DIKETONE COMPLEX supramolecular network crystal structure,rare earth nitrate,β-diketone,complex,supramolecular network
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